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We examine here a series of meso-phenyl porphyrin micro- and nanostructures. Optical absorption and emission spectroscopy imaging and atomic force microscopy are used to investigate the effect of peripheral groups in nano- and microstructures of 5,10,15,20-tetraphenylporphyrin (H2TPP) compared to three other phenylporphyrins, i.e. 5,10,15-triphenylporphyrin (H2-Tri-PP), 5,10-diphenylporphyrin (H25,10-BPP) and 5,15-diphenylporphyrin (H25,15-BPP) molecules. We show that nanospheres and nanorods are formed, the occurrence and properties of which are influenced by the number and position of the phenyl substituents.

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From the analysis of harmonic spectrum of conventional PWM techniques, it is observed that a high amount of energy is concentrated around the harmonics of switching frequencies as side bands resulting in acoustic noise, vibration and electromagnetic interference. These effects can be mitigated by spreading the spectrum and reducing the magnitude of harmonics around switching frequencies. This can be achieved by introducing the randomness in control signals. In this paper a simplified and more generalized carrier-based random pulse width modulation (RPWM) technique is presented for asymmetrical dual-inverter-fed vector-controlled induction motor drive. In the proposed RPWM technique a zero sequence signal is added to the commended reference signal to obtain the required modulating signal. The randomness is introduced in generating the zero-sequence signal. To validate the proposed RPWM technique, simulation and experimental studies are carried out and the results are presented.

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<span>Agriculture plays an important role in economic aspects in most countries like India. Numerous problems associated with farming are continuously affecting the actions that are happening in the country. A potential resolution for such issues to be eradicated, one should combine the technological advancements with current ongoing agricultural practices. Good agricultural practice will increase crop productivity and reduce unwanted water usage. Many authors have done research on temperature, nutrition, and pH-controlled systems. But no one concentrated on alert messages sent to the mobile phone. The main objective of the proposed system measures various natural aspects that use a global system for mobile communication (GSM) module that is connected to an Arduino to transfer the data that is obtained by the sensors to an internet of things (IoT) <a name="_Hlk93396762"></a>application programming interface (API) which is a kind of cloud computing of obtained data, this data can be analyzed if needed, and an alert short message service (SMS) is sent to the cell phone/mobile phone. The alert message can be done through conversational artificial intelligence (CAI). It is the collection of technologies behind triggering the message that will be sent automatically to the mobile as an SMS if any of the sensor values that are generating are not under already specified threshold values.</span>

Dual inverter fed open end winding induction motor (IM) drive offers many advantages over other multilevel inverter fed IM drives. Pulse width modulation (PWM) techniques are employed for the control of output voltage and frequency. Space vector base PWM techniques are popular among all the PWM techniques. A simplified space vector PWM method with simple and small look-up table approach is presented for dual inverter configuration. Moreover the proposed space vector based PWM technique provides freedom in selecting the center voltage vector (CVV) by which different PWM techniques will be derived. The implementation of all these PWM techniques is generalized by using a constant a o . The derived PWM techniques show superior performance in reducing the zero sequence voltage (ZSV) by maintaining the same quality of output voltage. The performance of all these PWM techniques are evaluated theoretically and verified in real time through dSPACE 1104 control board.

Conventional space vector pulse width modulation based asymmetrical dual inverter configuration produces high common mode voltage (CMV) variations. This CMV causes the flow of common mode current, which adversely affects the motor bearings and electromagnetic interference of nearby electronic systems. In this study, a simple and generalized carrier based pulse width modulation (PWM) technique is proposed for dual inverter configuration. This simple approach generates various continuous and discontinuous modulating signals based PWM algorithms. With the application of the discontinuous modulating signal based PWM algorithm to the asymmetrical dual inverter configuration, the CMV can be reduced with a slightly improved quality of output voltage. The performance of the continuous and discontinuous modulating signals based PWM algorithms is explored through both theoretical and experimental studies. Results show that the discontinuous modulating signal based PWM algorithm efficiently reduces the CMV and switching losses.