Liposomes containing the hydrogenase complex and the fumarate reductase complex isolated from Wolinefla (formerly Vibrio) succinogenes, together with vitamin KI catalyzed the electron transport from Hz to fumarate. With the fumarate reductase complex present in excess the activity of electron transport was close to that of the hydrogenase complex. Liposomes containing an ATP synthase in addition to the electron transport components catalyzed the phosphorylation of ADP driven by the electron transport.Electron transport Phoshorylation Liposome Fumarate reductase Hydrogenase
The easily accessible [2.2]paracyclophane moiety should find its use in medicinal chemistry as it is a pharmacophoric substituent with the interesting feature of planar chirality.
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