for all cases, but generally becomes smaller for a faster reaction and smaller diffusion coefficient. However, values of µ from 10~1 2 to 10~3 45cm. will at least predict the order of magnitude of the rate constants for the cases where the re-action involves a reduction product of the electrode, and values closer to 10~7 cm. for reactions that precede the electrode reduction. Chicago, Illinois
Conductance data are reported for hydrogen chloride and ammonium chloride in dimethylformamide, the limiting value for the acid being 70, and that for the salt 90.6. The observed limiting slopes of the Kohlrausch plots for these solutions show large deviations from those calculated theoretically by means of the Onsager equation.
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