In this article, the heavy metals in soils for agricultural activities were analyzed statistically. Ten (10) soil samples were randomly taken across the agricultural zones in Odo-Oba, southwestern Nigeria. Ten (10) metals; namely: copper (Cu), lead (Pb), chromium (Cr), arsenic (As), zinc (Zn), cadmium (Cd), nickel (Ni), antimony (Sb), cobalt (Co) and vanadium (V) were determined and compared with the guideline values. When the values were compared with the international standard, none of the heavy metals in the study area exceeded the threshold limit. However, the maximum range of the samples showed that Cr and V exceeded the permissible limit which could be associated with ecological risk. The data can reveal the distributions of heavy metals in the agricultural topsoil of Odo-Oba, and can be used to estimate the risks associated with the consumption of crops grown on such soils.
Waste paper is known to be the major component of organic solid waste. In this research, waste paper was used as a feedstock for the production of fermentable sugar with the aid of two (2) microorganisms. The waste papers used included newspaper, office paper and foolscap paper. Enzymatic hydrolysis was carried out on the waste papers after the alkaline treatment using Aspergillus niger and Pseudomonas aeruginosa at different temperatures of 25 o C, 37 o C and 42 o C. The highest yield was obtained from the foolscap paper, which produced reducing sugar at a maximum concentration of 486.66 mg/L after two weeks using Pseudomonas aeruginosa at 37 o C. On the other hand, hydrolysing using Aspergillus niger, produced reducing sugar at a maximum concentration of 365 mg/L at an optimum temperature of 25 o C with office paper.
The size characteristics of atmospheric aerosol over the tropical region of Lagos, Southern Nigeria were investigated using two years of continuous spectral aerosol optical depth measurements via the AERONET station for four major bands i.e. blue, green, red and infrared. Lagos lies within the latitude of 6.465°N and longitude of 3.406°E. Few systems of dispersion model was derived upon specified conditions to solve challenges on aerosols size distribution within the Stokes regime. The dispersion model was adopted to derive an aerosol size distribution (ASD) model which is in perfect agreement with existing model. The parametric nature of the formulated ASD model shows the independence of each band to determine the ASD over an area. The turbulence flow of particulates over the area was analyzed using the unified number (Un). A comparative study via the aid of the Davis automatic weather station was carried out on the Reynolds number, Knudsen number and the Unified number. The Reynolds and Unified number were more accurate to describe the atmospheric fields of the location. The aerosols loading trend in January to March (JFM) and August to October (ASO) shows a yearly 15% retention of aerosols in the atmosphere. The effect of the yearly aerosol retention can be seen to partly influence the aerosol loadings between October and February.
In the quest for environmental remediation which involves eco-friendly synthetic routes, we herein report synthesis and modeling of silver nanoparticles (Ag NPs) and silver/nickel allied bimetallic nanoparticles (Ag/Ni NPs) using plant-extract reduction method. Secondary metabolites in the leaf extract of Canna indica acted as reducing agent. Electronic transitions resulted in emergence of surface plasmon resonance in the regions of 416 nm (Ag NPs) and 421 nm (Ag/Ni NPs) during optical measurements. Further characterizations were done using TEM and EDX. Antimicrobial activity of the nanoparticles against clinical isolates was highly significant as P < 0.05. These findings suggest application of Ag NPs as antibacterial agent against E. coli, S. pyogenes, and antifungal agent against C. albicans. Possible antibacterial drugs against S. pyogenes and E. coli can also be designed using Ag/Ni nanohybrid based on their strong inhibition activities. Similarly, the enhanced SPR in the nanoparticles is suggested for applications in optical materials, as good absorbers and scatters of visible light. Theoretical model clarified that the experiment observation on the relationship between metallic nanoparticles penetration through peptidoglycan layers and the activeness of microbial species depends on the nature of the nanoparticles and pore size of the layer.
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