Abstract. The Curiosity rover discovered fine--grained sedimentary rocks, inferred to represent an ancient lake, preserve evidence of an environment that would have been suited to support a Martian biosphere founded on chemolithoautotrophy. This aqueous environment was characterized by neutral pH, low salinity, and variable redox states of both iron and sulfur species. C, H, O, S, N, and P were measured directly as key biogenic elements, and by inference N and P are assumed to have been available. The environment likely had a minimum duration of hundreds to tens of thousands of years. These results highlight the biological viability of fluvial--lacustrine environments in the post--Noachian history of Mars.

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X-ray diffraction analysis of the Rocknest scoop sample is described in (23); similar analyses were performed for John Klein and Cumberland. John Klein and Cumberland were the first two drill samples collected by Curiosity. All scooped or drilled samples pass through the Collection and Handling for In situ Martian Rock Analysis (CHIMRA) sample collection and processing system (10). All powders for X-ray diffraction are processed through a 150-m sieve before delivering a portion to the CheMin inlet funnel.The sieved drill powders were placed into sample cells with 6 μm thick Mylar® windows. Mylar® contributes a minor, broad scattering signature in diffraction patterns that is generally "swamped" by diffraction from the loaded sample. In addition, an aluminized light shield also contributes "peaks" to the observed diffraction patterns. Only ~10 mm 3 of material is required to fill the active volume of the sample cell, which is a disc-shaped volume 8 mm in diameter and 175 m thick. A collimated ∼70 μm diameter X-ray beam illuminates the center of the sample cell. A piezoelectric vibration system on each cell pair shakes the material during analysis, causing grains in the cell to pass through the X-ray beam in random orientations.CheMin measures XRD and XRF data simultaneously using Co radiation in transmission geometry (11). The instrument operates in single-photon counting mode so that between each readout the majority of CCD pixels are struck by either a single X-ray photon or by no photons. In this way, the system can determine both the energy of the photons striking the CCD (XRF) and the two-dimensional (2-D) position of each photon (XRD). The energy and positional information of detected photons in each frame are summed over repeated 10-sec measurements into a "minor frame" of 30 min of data (180 frames). The 2-D distribution of Co K X-ray intensity represents the XRD pattern of the sample. Circumferential integration of these rings, corrected for arc length, produces a conventional 1-D XRD pattern. For conversion of the 2-D CCD pattern to a 1-D pattern we have used FilmScan © software from Materials Data, Inc.CheMin generally operates for only a few hours each night, when the CCD can be cooled to its lowest temperature, collecting as many minor frames as possible for the available analysis time, usually five to seven per night. XRD data were acquired over multiple nights for the John Klein and Cumberland drill samples to provide acceptable counting statistics. Total data collection times were 33.9 hr for John Klein and 20.2 hr for Cumberland. The data for individual minor frames and for each night's analysis were examined separately, and there was no evidence of any changes in instrumental parameters as a function of time over the duration of these analyses. Before sample delivery and analysis, the empty cell was analyzed to confirm that it was indeed empty before receiving the sample. The flight instrument was calibrated on the ground before flight using a quartz-beryl standard, and measurement of this st...

Abstract. The Thermal Emission Spectrometer (TES) investigation on Mars GlobalThe TES data are calibrated to a 1-o-precision of 2.5 -6 X 10 -8 W cm -2 sr-1/cm -•, 1.6 x 10 -6 W cm -2 sr -•, and -0.5 K in the spectrometer, visible/near-IR bolometer, and IR bolometer, respectively_. These instrument subsections are calibrated to an absolute accuracy of-4 x 10 -8 W cm -2 sr-•/cm -• (0.5 K at 280 K), 1-2%, and -1-2 K, respectively. Global mapping of surface mineralogy at a spatial resolution of 3 km has shown the following: (1) The mineralogic composition of dark regions varies from basaltic, primarily plagioclase feldspar and clinopyroxene, in the ancient, southern highlands to andesitic, dominated by plagioclase feldspar and volcanic glass, in the younger northern plains. (2) Aqueous mineralization has produced gray, crystalline hematite in limited regions under ambient or hydrothermal conditions; these deposits are interpreted to be in-place sedimentary rock formations and indicate that liquid water was stable near the surface for a long period of time. (3) There is no evidence for large-scale (tens of kilometers) occurrences of moderate-grained (>50-•m) carbonates exposed at the surface at a detection limit of -10%. (4) Unweathered volcanic minerals dominate the spectral properties of dark regions, and weathering products, such as clays, have not been observed anywhere above a detection limit of -10%; this lack of evidence for chemical weathering indicates a geologic history dominated by a cold, dry climate in which mechanical, rather than chemical, weathering was the significant form of erosion and sediment production. (5) There is no conclusive evidence for sulfate minerals at a detection limit of -15%. The polar region has been studied with the following major conclusions: (1) Condensed CO2 has three distinct end-members, from fine-grained crystals to slab ice. (2) The growth and retreat of the polar caps observed by MGS is virtually the same as observed by Viking 12 Martian years ago. (3) Unique regions have been identified that appear to differ primarily in the grain size of CO2; one south polar region appears to remain as black slab CO2 ice throughout its sublimation. (4) Regional atmospheric dust is common in localized and regional dust storms around the margin and interior of the southern cap. Analysis of the thermophysical properties of the surface shows that (1) the spatial pattern of albedo has changed since Viking observations, (2) a unique cluster of surface materials with intermediate inertia and albedo occurs that is distinct from the previously identified lowinertia/bright and high-inertia/dark surfaces, and (3) localized patches of high-inertia material have been found in topographic lows and may have been formed by a unique set of aeolian, fluvial, or erosional processes or may be exposed bedrock.• •Raytheon Santa Barbara Remote Sensing, Goleta, California. IntroductionThe Thermal Emission Spectrometer (TES) experiment is designed to address a wide range of science objectives, including the de...

[1] The Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) is a hyperspectral imager on the Mars Reconnaissance Orbiter (MRO) spacecraft. CRISM consists of three subassemblies, a gimbaled Optical Sensor Unit (OSU), a Data Processing Unit (DPU), and the Gimbal Motor Electronics (GME). CRISM's objectives are (1) to map the entire surface using a subset of bands to characterize crustal mineralogy, (2) to map the mineralogy of key areas at high spectral and spatial resolution, and (3) to measure spatial and seasonal variations in the atmosphere. These objectives are addressed using three major types of observations. In multispectral mapping mode, with the OSU pointed at planet nadir, data are collected at a subset of 72 wavelengths covering key mineralogic absorptions and binned to pixel footprints of 100 or 200 m/pixel. Nearly the entire planet can be mapped in this fashion. In targeted mode the OSU is scanned to remove most along-track motion, and a region of interest is mapped at full spatial and spectral resolution (15-19 m/pixel, 362-3920 nm at 6.55 nm/channel). Ten additional abbreviated, spatially binned images are taken before and after the main image, providing an emission phase function (EPF) of the site for atmospheric study and correction of surface spectra for atmospheric effects. In atmospheric mode, only the EPF is acquired. Global grids of the resulting lower data volume observations are taken repeatedly throughout the Martian year to measure seasonal variations in atmospheric properties. Raw, calibrated, and map-projected data are delivered to the community with a spectral library to aid in interpretation.

Living systems produce more than 90% of Earth's atmospheric methane; the balance is of geochemical origin. On Mars, methane could be a signature of either origin. Using high-dispersion infrared spectrometers at three ground-based telescopes, we measured methane and water vapor simultaneously on Mars over several longitude intervals in northern early and late summer in 2003 and near the vernal equinox in 2006. When present, methane occurred in extended plumes, and the maxima of latitudinal profiles imply that the methane was released from discrete regions. In northern midsummer, the principal plume contained approximately 19,000 metric tons of methane, and the estimated source strength (>/=0.6 kilogram per second) was comparable to that of the massive hydrocarbon seep at Coal Oil Point in Santa Barbara, California.

Phyllosilicates, a class of hydrous mineral first definitively identified on Mars by the OMEGA (Observatoire pour la Mineralogie, L'Eau, les Glaces et l'Activitié) instrument 1,2 , preserve a record of the interaction of water with rocks on Mars. Global mapping showed that phyllosilicates are widespread but are apparently restricted to ancient terrains and a relatively narrow range of mineralogy (Fe/Mg and Al smectite clays). This was interpreted to indicate that phyllosilicate formation occurred during the Noachian (the earliest geological era of Mars), and that the conditions necessary for phyllosilicate formation (moderate to high pH and high water activity 3 ) were specific to surface environments during the earliest era of Mars's history 4 . Here we report results from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) 5 of phyllosilicate-rich regions. We expand the diversity of phyllosilicate mineralogy with the identification of kaolinite, chlorite and illite or muscovite, and a new class of hydrated silicate (hydrated silica). We observe diverse Fe/Mg-OH phyllosilicates and find that smectites such as nontronite and saponite are the most common, but chlorites are also present in some locations. Stratigraphic relationships in the Nili Fossae region show olivine-rich materials overlying phyllosilicate-bearing units, indicating the cessation of aqueous alteration before emplacement of the olivine-bearing unit. Hundreds of detections of Fe/Mg phyllosilicate in rims, ejecta and central peaks of craters in the southern highland Noachian cratered terrain indicate excavation of altered crust from depth. We also find phyllosilicate in sedimentary deposits clearly laid by water. These results point to a rich diversity of Noachian environments conducive to habitability.High-spatial-resolution, precision-pointing and nested observations of CRISM 5 , the Context Imager (CTX) 6 , and the High Resolution Imaging Science Experiment (HiRISE) 7 instruments on the Mars Reconnaissance Orbiter (MRO) resolve mineralogical, stratigraphic and geological relationships for phyllosilicate deposits. This combination of instruments permits mineralogical mapping at 18 m per pixel with CRISM linked with metre-scale geomorphology from CTX and HiRISE. We focus here on the stratigraphic setting of phyllosilicate-bearing rocks in three regions and report the detection of phyllosilicate in sedimentary settings.We identify two principal classes of mineral in the CRISM data on the basis of observed absorptions: Al phyllosilicates and the more common and spatially dominant Fe/Mg phyllosilicates. The increased spatial and spectral resolutions of CRISM have revealed a diversity of absorption band shapes, positions and combinations indicating variations in phyllosilicate type and composition ( Fig. 1; see Methods for processing and identification details). Most spectra show a band at ,1.4 mm from the overtone of the OH stretch, a strong 1.9-mm H 2 O band and absorptions near 2.28-2.30 mm (for example, spectrum 3 in Fig. 1b), which ...

We have produced a multiannual climatology of airborne dust from Martian year 24 to 31 using multiple datasets of retrieved or estimated column optical depths. The datasets are based on observations of the Martian atmosphere from April 1999 to July 2013 made by different orbiting instruments: the Thermal Emission Spectrometer (TES) aboard Mars Global Surveyor, the Thermal Emission Imaging System (THEMIS) aboard Mars Odyssey, and the Mars Climate Sounder (MCS) aboard Mars Reconnaissance Orbiter (MRO). The procedure we have adopted consists of gridding the available retrievals of column dust optical depth (CDOD) from TES and THEMIS nadir observations, as well as the estimates of this quantity from MCS limb observations. Our gridding method calculates averages on a regularly spaced, but possibly incomplete, spatio-temporal grid, using an iterative procedure weighted in space, time, and retrieval uncertainty. In order to evaluate strengths and weaknesses of the resulting gridded maps, we associate values of weighted standard deviation with every grid point average, and compare with independent observations of CDOD by PanCam cameras and Mini-TES spectrometers aboard the Mars Exploration Rovers ("Spirit" and "Opportunity"), as well as the Compact Reconnaissance Imaging Spectrometer for Mars aboard MRO. We have statistically analyzed the irregularly gridded maps to provide an overview of the dust climatology on Mars over eight years, specifically in relation to its interseasonal and interannual variability. Finally, we have produced multiannual, regular daily maps of CDOD by spatially interpolating the irregularly gridded maps using a kriging method. These synoptic maps are used as dust scenarios in the Mars Climate Database version 5, and are useful in many modelling applications in addition to forming a basis for instrument intercomparisons. The derived dust maps for the eight available Martian years (currently version 1.5) are publicly available and distributed with open access.