2000 stereochemistry stereochemistry (general, optical resolution) O 0030 34 -023 Isomerization of Allyl Ethers of Diols and Triols Catalyzed by Ruthenium Complexes. -The synthesis of various propenyl ethers via Ru-catalyzed isomerization of the corresponding allyl ethers is reported. The isomerization is inhibited in the presence of triple bonds and unprotected allylic hydroxyl groups. -(KROMPIEC, S.; ANTOSZCZYSZYN, M.; URBALA, M.; BIEG, T.; Pol.
The novel class of cationic UV-curable allyl ether functionalized siloxane monomers type CH2=CH-CH2-O-R-O-Si(CH3)3 and type CH2=CH-CH2-O-R-O-Si(CH3)2-O-R-CH2-CH=CH2 have been synthesized in excellent yields in short times at ambient temperature conditions in the absence of any added catalyst by the classical silylation reactions of homoallyloxyalcohols with chlorosilanes under ultrasonic irradiation.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.