Mossbauer and Ac-susceptibility measurementshave been carriedout on the alloy series FeAl,_,Mn, within the range 0.05 S x b 0.40. M6ssbauer spectra reveal the presence of electron charge density and magnetic hypefine field (BM) distributions at two iron sites. Thecharge density rises linearly with Mn concentration while B,,increases non-linearly with x indicating a polarized spin density of the itinerant electrons at the Fe nucleus due to the near neighbouring Fe and Mn magnetic moments. The onset of magnetism is explained by the formation of magnetic moment at the iron atom when AI atoms are removed and by the nearest neighbouring iron clustering. Magnetic measurements indicate the presence of mictomagneticclusters and show a transition from paramagneticstate tomagneticglass state for all the alloys. NO onset of ferromagnetism with increasing x was observed even at the concentration x = 0.4, in contrast to that observed in FeAI, $U, at a lower concentration x = 0.325. Comparison of the transition temperatures obtained from Mossbauer and ACsusceptibility measurements indicate relaxations of the magnetic clusters.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.