This paper provides a comprehensive assessment of the sliding and abrasive wear behaviour of WC-10Co4Cr hardmetal coatings, representative of the existing state-of-the-art. A commercial feedstock powder with two different particle size distributions was sprayed onto carbon steel substrates using two HVOF and two HVAF spray processes.
Sliding wear evaluation of nanostructured coatings deposited by Suspension High Velocity OxyFuel (S-HVOF) and conventional HVOF (Jet Kote (HVOF-JK) and JP5000 (HVOF-JP)) spraying were evaluated. S-HVOF coatings were nanostructured and deposited via an aqueous based suspension of the WC-Co powder, using modified HVOF (TopGun) spraying. Microstructural evaluations of these hardmetal coatings included X-ray Diffraction (XRD) and Scanning Electron Microscopy (SEM) equipped with Energy Dispersive X-ray Spectroscopy (EDX). Sliding wear tests on coatings were conducted using a ball-on-flat test rig against steel, silicon nitride (Si 3 N 4 ) ceramic and WC-6Co balls. Results indicated that nanosized particles inherited from the starting powder in S-HVOF spraying were retained in the resulting coatings. Significant changes in the chemical and phase composition were observed in the S-HVOF coatings. Despite decarburization, the hardness and sliding wear resistance of the S-HVOF coatings was comparable to the HVOF-JK and HVOF-JP coatings. The sliding wear performance was dependent on the ball-coating test couple. In general a higher ball wear rate was observed with lower coating wear rate. Comparison of the total (ball and coating) wear rate indicated that for steel and ceramic balls, HVOF-JP coatings performed the best followed by the S-HVOF and HVOF-JK coatings. For the WC-Co ball tests, average performance of S-HVOF was better than that of HVOF-JK and HVOF-JP coatings. Changes in sliding wear 1 Corresponding author R.Ahmed@hw.ac.uk 2 behavior were attributed to the support of metal matrix due to relatively higher tungsten, and uniform distribution of nanoparticles in the S-HVOF coating microstructure. The presence of tribofilm was also observed for all test couples.
The tribological properties of part surfaces, namely their wear resistance and friction properties, are decisive in many cases for their proper function. To improve surface properties, it is possible to create hard, wear-resistant coatings by thermal spray technologies. With these versatile coating preparation technologies, part lifetime, reliability, and safety can be improved. In this study, the tribological properties of the HVOF-sprayed coatings WC-17%Co, WC-10%Co4%Cr, WC-15% NiMoCrFeCo, Cr 3 C 2 -25%NiCr, (Ti,Mo)(C,N)-37%NiCo, NiCrSiB, and AISI 316L and the plasma-sprayed Cr 2 O 3 coating were compared with the properties of electrolytic hard chrome and surface-hardened steel. Four different wear behavior tests were performed; the abrasive wear performance of the coatings was assessed using a dry sand/ rubber wheel test according to ASTM G-65 and a wet slurry abrasion test according to ASTM G-75, the sliding wear behavior was evaluated by pin-on-disk testing according to ASTM G-99, and the erosion wear resistance was measured for three impact angles. In all tests, the HVOF-sprayed hardmetal coatings exhibited superior properties and can be recommended as a replacement for traditional surface treatments. Due to its tendency to exhibit brittle cracking, the plasma-sprayed ceramic coating Cr 2 O 3 can only be recommended for purely abrasive wear conditions. The tested HVOF-sprayed metallic coatings, NiCrSiB and AISI 316L, did not have sufficient wear resistance compared with that of traditional surface treatment and should not be used under more demanding conditions. Based on the obtained data, the application possibilities and limitations of the reported coatings were determined.
This paper provides a comprehensive characterisation of HVOF-and HVAF-sprayed Cr 3 C 2-25 wt.% NiCr hardmetal coatings. One commercial powder composition with two different particle size distributions was processed using five HVOF and HVAF thermal spray systems. All coatings contain less Cr 3 C 2 than the feedstock powder, possibly due to the rebound of some Cr 3 C 2rich particles during high-velocity impact onto the substrate. Dry sand-rubber wheel abrasive wear testing causes both grooving and pull-out of splat fragments. Mass losses depend on inter-and intra-lamellar cohesion, being higher (Z 70 mg after a wear distance of 5904 m) for the coatings deposited with the coarser feedstock powder or with one type of HVAF torch. Sliding wear at room temperature against alumina involves shallower abrasive grooving, small-scale delamination and carbide pull-outs, and it is controlled by intra-lamellar cohesion. The coatings obtained from the fine feedstock powder exhibit the lowest wear rates (E5x10 À 6 mm 3 /(Nm)). At 400°C, abrasive grooving dominates the sliding wear behaviour; wear rates increase by one order of magnitude but friction coefficients decrease from E0.7 to E 0.5. The thermal expansion coefficient of the coatings (11.08x10 À 6°C À 1 in the 30-400°C range) is sufficiently close to that of the steel substrate (14.23x 10 À 6°C À 1) to avoid macro-cracking.
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