As promising candidates in the field of artificial muscles, ionic‐polymer–metal composites (IPMCs) still cannot simultaneously provide large deformations and fast responses, which has limited their practical applications. In this study, to overcome this issue, a Nafion‐based IPMC with high‐quality metal electrodes is fabricated via novel isopropanol‐assisted electroless plating. The IPMC exhibits a large tip displacement (35.3 mm, 102.3°) under a low direct‐current driving voltage and ultrafast response (>10 Hz) under an alternating‐current (AC) voltage. Furthermore, the simultaneous integration of a large deformation and fast response can be achieved by the IPMC under a high‐frequency (19 Hz) AC voltage, where the largest bending amplitude is 5.9 mm and the highest bending speed reaches 224.2 mm s−1 (596.2° s−1). Additionally, the lightweight IPMC exhibits a decent load capacity and can lift objects 20 times heavier. The outstanding performances of the Nafion IPMC are demonstrated by mimicking biological motions such as petal opening/closing, tendril coiling/uncoiling, and high‐frequency wing flapping. This study paves the way for the fabrication of lightweight actuators with simultaneous large displacements and fast responses for promising applications in biomedical devices and bioinspired robotics.
Herein, we developed a nanocomposite membrane with synergistic photodynamic therapy and photothermal therapy antibacterial effects, triggered by a single near-infrared (NIR) light illumination. First, upconversion nanoparticles (UCNPs) with a hierarchical structure (UCNPs@TiO2) were synthesized, which use NaYF4:Yb,Tm nanorods as the core and TiO2 nanoparticles as the outer shell. Then, nanosized graphene oxide (GO), as a photothermal agent, was doped into UCNPs@TiO2 core–shell nanoparticles to obtain UCNPs@TiO2@GO. Afterward, the mixture of UCNPs@TiO2@GO in poly(vinylidene) fluoride (PVDF) was applied for electrospinning to generate the nanocomposite membrane (UTG-PVDF). Generation of reactive oxygen species (ROS) and changes of temperature triggered by NIR action were both investigated to evaluate the photodynamic and photothermal properties. Upon a single NIR light (980 nm) irradiation for 5 min, the nanocomposite membrane could simultaneously generate ROS and moderate temperature rise, triggering synergistic antibacterial effects against both Gram-positive and -negative bacteria, which are hard to be achieved by an individual photodynamic or photothermal nanocomposite membrane. Additionally, the as-prepared membrane can effectively restrain the inflammatory reaction and accelerate wound healing, thus exhibiting great potentials in treating infectious complications in wound healing progress.
Currently, four-dimensional (4D) printing programming methods are mainly structure-based, which usually requires more than one material to endow products with site-specific attributes. Here, we propose a new 4D printing programming approach that enables site-specific shape-morphing behaviors in a single material by regulating the printing parameters. Specifically, a direct ink writing three-dimensional (3D) printer with the ability to change printing parameters (e.g., deposition speed) on the fly is reported. By site-specifically adjusting print speed and print path to control the local nematic arrangements of printed liquid crystal elastomers (LCEs), the shape-morphing behaviors of the LCEs can be successfully programmed. In this way, locally programmed popping-up, self-assembling, and oscillating behaviors can be designed by varying the print speed in specific regions. Snake-like curling is realized by uniformly boosting the print speed in a single line. Furthermore, two theories and an ultrasound image diagnostic apparatus are employed to reveal the mechanism behind this behavior. This work provides a feasible way to realize the gradient transition of material properties through a single material. It broadens the design space and pushes the envelope of 4D printing, which is expected to be helpful in the fabrication of soft robotics and flexible electronics.
Functional electronics has promising applications, including highly advanced human-interactive devices and healthcare monitoring. Here, we present a unique printable micron-scale cracked strain sensor (PMSCSS), which is bioinspired by a spider's crack-shaped lyriform slit organ. The PMSCSS is fabricated by a facile process that utilizes screen-printing to coat carbon black (CB) ink onto a paper substrate. With a certain bending radius, a cracked morphology emerged on the solidified ink layer. The working principle of the PMSCSS is prominently attributed to the strain-dependent variation in resistance due to the reconnection-disconnection of the crack fracture surfaces. The device shows appealing performances, with superfast response times (∼0.625 ms) and high sensitivity (gauge factor = 647). The response time surpasses most recent reports, and the sensitivity is comparable. We demonstrate the application of the PMSCSSs as encoders, which have good linearity and negligible hysteresis. Also, the sensor can be manipulated as a vibration detector by monitoring human-motion disturbances. According to the sensory information, some details of movements can be deduced.
Twenty-nine species (24 genera, 6 families) of butterflies typical and common in northeast China were selected to make qualitative and quantitative studies on the pattern, hydrophobicity and hydrophobicity mechanism by means of scanning electron microscopy and contact angle measuring system. The scale surface is composed of submicro-class vertical gibbosities and horizontal links. The distance of scale is 48-91 μm, length 65-150 μm, and width 35-70 μm. The distance of submicro-class vertical gibbosities on scale is 1.06-2.74 μm, height 200-900 nm, and width 200-840 nm. The better hydrophobicity on the surface of butterfly wing (static contact angle 136.3°-156.6°) is contributed to the co-effects of micro-class scale and submicro-class vertical gibbosities on the wing surface. The Cassie equation was revised, and new mathematical models and equations were established.bionic, non-smooth surface, self-cleaning, super-hydrophobicity, butterfly, scale, mathematical model, micro/nano structure The hydrophobicity and self-cleaning characteristic on object surface have been found to have very wide applications in industrial, agricultural, domestic and military fields, such as snow proof, water proof, fog proof, pollution guarding, anti-oxidation, aerobat, submarine, radar, etc. Through long-term evolution and natural selection, the surface of butterfly wing is hydrophobic and selfcleaning. When rain or snow drops on the surface, a butterfly can self-clean, while it needs several times of effort to clean an artificial surface with the same area [1][2][3][4] . Cassie and Baxter [5] proposed that a water droplet cannot fill up the groove on rough surface, air can remain trapped below the drops, and the heterogeneous surface is composed of solid and air, and established the Cassie Model in 1944. Based on 200 water-repellent plant species, in 1997 Neinhuis and Barthlott [6] surveyed micromorphological characteristics of anti-adhesive plant surfaces, and studied the characterization and distribution of water-repellent, self-cleaning plant surfaces. Also in 1997 Barthlott and Neinhuis [7] used 9 kinds of fine powder (dried soil, quartz dusts, etc.) to artificially contaminate leaf surface of 8 plant species. Following contamination, the specimens were subjected to natural and artificial rain of various droplet sizes. On water-repellent surfaces, water contracted to form spherical droplets which ran off the leaf very quickly, even at slight angles of inclination (<5°), without leaving any residue. This self-cleaning mechanism is independent of their chemical nature or size. Due to hydrophobic surface components in connection with a microscopic roughness, many plant surfaces provide a very effective anti-adhesive property against particulate contamination. This selfcleaning mechanism is called the Lotus-Effect. In 1998 Neinhuis and Barthlott [8] studied the seasonal changes of leaf surface contamination in beech (Fagus sylvatica), oak (Quercus robur) and ginkgo (Ginkgo biloba) in relation to leaf micromorphology and wettability. ...
Footprints are the most direct source of evidence about locomotor biomechanics in extinct vertebrates. One of the principal suppositions underpinning biomechanical inferences is that footprint geometry correlates with dynamic foot pressure, which, in turn, is linked with overall limb motion of the trackmaker. In this study, we perform the first quantitative test of this longstanding assumption, using topological statistical analysis of plantar pressures and experimental and computer-simulated footprints. In computer-simulated footprints, the relative distribution of depth differed from the distribution of both peak and pressure impulse in all simulations. Analysis of footprint samples with common loading inputs and similar depths reveals that only shallow footprints lack significant topological differences between depth and pressure distributions. Topological comparison of plantar pressures and experimental beach footprints demonstrates that geometry is highly dependent on overall print depth; deeper footprints are characterized by greater relative forefoot, and particularly toe, depth than shallow footprints. The highlighted difference between 'shallow' and 'deep' footprints clearly emphasizes the need to understand variation in foot mechanics across different degrees of substrate compliance. Overall, our results indicate that extreme caution is required when applying the 'depth equals pressure' paradigm to hominin footprints, and by extension, those of other extant and extinct tetrapods.
Grasping and manipulation are fundamental ways for many creatures to interact with their environments. Different morphologies and grasping methods of “grippers” are highly evolved to adapt to harsh survival conditions. For example, human hands and bird feet are composed of rigid frames and soft joints. Compared with human hands, some plants like Drosera do not have rigid frames, so they can bend at arbitrary points of the body to capture their prey. Furthermore, many muscular hydrostat animals and plant tendrils can implement more complex twisting motions in 3D space. Recently, inspired by the flexible grasping methods present in nature, increasingly more bio‐inspired soft grippers have been fabricated with compliant and soft materials. Based on this, the present review focuses on the recent research progress of bio‐inspired soft grippers based on impactive gripping. According to their types of movement and a classification model inspired by biological “grippers”, soft grippers are classified into three types, namely, non‐continuum bending‐type grippers, continuum bending‐type grippers, and continuum twisting‐type grippers. An exhaustive and updated analysis of each type of gripper is provided. Moreover, this review offers an overview of the different stiffness‐controllable strategies developed in recent years.
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