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Hydrochar obtained after hydrothermal carbonization (HTC) of Lepironia articulata (LA) was modified into biochar by reacting with a specific amount of KOH in a tubular reactor under slow pyrolysis. The physical and chemical properties of the hydrochar and modified biochar were characterized. The performance of modified biochar (LABC) was investigated through batch sorption experiments. Removal (%) and the maximum adsorption capacity (q max ) of Cr(VI) onto LABC increased up to 98.9% and 28.75 mg/g relative to 63.44% and 21.90 mg/g in unmodified hydrochar (LAHC) at pH 2.0, 313 K, and 200 mg/L, respectively. The sorption kinetics uptake data were best interpreted with pseudo-second-order model, and sorption isotherm was simulated with the Langmuir adsorption model. The thermodynamic parameters confirm the adsorption process to be an endothermic, spontaneous, and increased disorder. The overall results revealed that LABC can be utilized as an environmentally friendly, inexpensive, and effective adsorbent in Cr(VI) removal. • Practitioner points• Hydrochar and modified biochar prepared from a tropical biomass (Lepironia articulata) were successfully used for the removal of Cr(VI) from aqueous solution. • Increased specific surface was obtained by applying chemical modification with alkali treatment, contributing to effectiveness as adsorbent. • Dimensionless K c was estimated from the Langmuir fits and then used to estimate thermodynamics of adsorption. • The signs of ∆H°, ∆G°, and ∆S° indicate that the adsorption of Cr(VI) onto LABC was an endothermic, spontaneous, and increased disorder.

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Sorption studies were carried out to investigate removal of 2.4-dichlorophenol (2.4-DCP) from aqueous solution in a fl uidized bed by two types of adsorbent mixtures: BC (Bamboo char plus Calcium sulphate), and HBC (Hydroxyapatite plus Bamboo char plus Calcium sulphate); both manufactured in ball shape. The main material bamboo char was characterized by FTIR, DTA and SEM. The adsorption experiments were conducted in a fl uidized bed circulation column. Adsorption, isotherms and kinetic studies were established under 180 min operating process time, at different initial 2.4-DCP solution concentrations ranging from 5-10 mg/L, and at different fl ow rates ranging from 0.25-0.75 L/min. The data obtained fi tted well for both the Langmuir and Freundlich isotherm models; indicating favorable condition of monolayer adsorption. The kinetics of both adsorbents complies with the pseudo second-order kinetic model. BC was proven a new effective composite and low cost adsorbent which can be applied in the fi eld of wastewater treatment, and it can also play an important role in industry water treatment.