Herein, we report an allyl-imidazolium ionic liquid decorated COF and its covalent composite COF@chitosan aerogel, which were shown to be excellent selective CO2 adsorbents and chemical conversion catalysts.

A bifunctional robust and highly porous imidazolium-based ionic liquid decorated UiO-67 type MOF (UiO-67-IL, 1) was successfully constructed via solvothermal assembly of the imidazolium-based ligand and Zr(IV) ions. It exhibits a highly selective adsorption for CO over CH and N. Furthermore, 1 herein can be used as a highly active heterogeneous catalyst for CO cycloaddition with epoxides under atmospheric pressure with or without cocatalyst TBAB (n-BuNBr).

A Pd nano particle (NP)-loaded and nano metal-organic framework (NMOF)-based Pickering emulsifier is reported. The poly[2-(diethylamino)ethyl methacrylate)] (PDEAEMA) chains were grafted onto UiO-66-type NPs via a postsynthetic approach to generate PDEAEMA-g-UiO-66 NMOF (termed as MOF-3). The Pd NPs-loaded Pd@MOF-3 was synthesized via solution impregnation. Stable toluene-in-water Pickering emulsion was prepared with emulsifier Pd@MOF-3. Notably, the obtained Pd@MOF-3 is pH-responsive, and it is able to trigger the emulsification (at neutral condition) and demulsification (at acidic condition) of toluene droplets. Furthermore, it can be a highly active interfacial catalyst to effectively promote one-pot Knoevenagel condensation-hydrogenation cascade reaction at ambient conditions. The pH-responsive property allowed it to be in situ separated and recycled by demulsifying via simply tuning the pH value at the end of the reaction. This smart Pickering emulsion catalytic system is robust, and it can be recycled at least five times without loss of its catalytic activity.

Carbon dioxide capture and transformation are of great importance to make cuts in greenhouse gas emissions. Nanometal-organic frameworks (NMOFs) could serve as ideal fillers for polymer membranes owing to their structural diversity and regulable microenvironment of the nanocage. Herein, a bifunctional, robust, and chemically cross-linked NMOF-based membrane was successfully constructed by the postsynthetic polymerization of imidazolium-based ionic liquid (IL)-decorated UiO-66 type nanoparticles (NPs) and the isocyanate-terminated polyurethane oligomer under mild conditions. The IL-modified MOF-polymer membranes exhibit a highly selective adsorption for CO over N and CH. In addition, the obtained membrane can also be a highly active heterogeneous catalyst for CO transformation by cycloaddition with epoxide under an ambient pressure.

Chronic wound infections resulting from severe bacterial invasion have become a major medical threat worldwide. Herein, we report a large-area, homogeneous, and self-standing porphyrin-covalent organic framework (COF)-based membrane with encapsulated ibuprofen (IBU) via an in situ interfacial polymerization and impregnation approach. The obtained IBU@DhaTph-membrane exhibits highly effective antibacterial and anti-inflammatory effects via synergistic light-induced singlet oxygen ( 1 O 2 ) generation and controllable IBU release, which is well supported by in vitro experiments. In addition, the IBU@DhaTph-membrane-based biocompatible "band-aid" type dressing is fabricated, and its excellent anti-infection and tissue remodeling activities are fully evidenced by in vivo chronic wound-healing experiments. This study may inspire and promote the fabrication of many more new types of COF-based multifunctional biomaterials for various skin injuries in clinical medicine.

Pd NP loaded COF-chitosan aerogels with desired shapes can be used to build highly efficient continuous flow-through microreactors to catalyse CB dechlorination in water at room temperature.

A quinoline-linked and ionic liquid-decorated covalent organic framework was prepared by incorporation of a multicomponent Povarov reaction and postsynthetic modification. The imidazolium and sulfonic acid-decorated COF-IM-SO 3 H can be a highly efficient Brønsted acid catalyst to promote the Biginelli reaction under solvent-free conditions in a heterogeneous way. In addition, a scaled-up Biginelli reaction has been readily realized over a COF-IM-SO 3 H@chitosan aerogel-based cup reactor.

A UiO-66-MOF-based membrane UiO-66-TEM (1) was prepared by the assembly of methacrylamide-decorated UiO-66-NH-Met with a thiol side chain-attached polysiloxane (PSI-SH) via a photoinduced thiol-ene click reaction. The obtained membrane 1 can be a platform to support Au nanoparticles (Au NPs) to generate an Au-MOF-polymer composite membrane Au@UiO-66-TEM (2). 1 and 2 can be used to build highly efficient continuous flow-through membrane reactors for Knoevenagel condensation of 4-nitrobenzaldehyde with malononitrile and 4-nitrophenol (4-NP) reduction at ambient temperature, respectively.