The mid-infrared spectrum contains rich diagnostics to probe the physical properties of galaxies, among which the pervasive emission features from polycyclic aromatic hydrocarbons (PAHs) offer promising means of estimating the star formation rate (SFR) relatively immune from dust extinction. This paper investigates the effectiveness of PAH emission as a SFR indicator on subkiloparsec scales by studying the Spitzer/IRS mapping-mode observations of the nearby grand-design spiral galaxy M51. We present a new approach of analyzing the spatial elements of the spectral data cube that simultaneously maximizes spatial resolution and spatial coverage, while yielding reliable measurements of the total, integrated 5–20 μm PAH emission. We devise a strategy of extracting robust PAH emission using spectra with only partial spectral coverage, complementing missing spectral regions with properly combined mid-infrared photometry. We find that in M51 the PAH emission correlates tightly with the extinction-corrected far-ultraviolet, near-ultraviolet, and Hα emission, from scales of ∼0.4 kpc close to the nucleus to 6 kpc out in the disk of the galaxy, indicating that PAH serves as an excellent tracer of SFR over a wide range of galactic environments. But regional differences exist. Close to the active nucleus of M51 the 6.2 μm feature is weaker, and the overall level of PAH emission is suppressed. The spiral arms and the central star-forming region of the galaxy emit stronger 7.7 and 8.6 μm PAH features than the inter-arm regions.

We combined mapping-mode mid-infrared Spitzer spectra with complementary infrared imaging to perform a spatially resolved study of polycyclic aromatic hydrocarbon (PAH) emission from the central regions of 66 nearby galaxies, roughly evenly divided into star-forming systems and low-luminosity active galactic nuclei (AGNs). In conjunction with similar measurements available for quasars, we aim to understand the physical properties of PAHs across a broad range of black hole accretion power, with the goal of identifying observational diagnostics that can be used to probe the effect of AGNs on the host galaxy. Whereas the PAH emission correlates tightly with far-ultraviolet luminosity in star-forming regions, the spatially resolved regions of AGNs tend to be PAH deficient. Moreover, AGN regions exhibit on average smaller PAH 6.2 μm/7.7 μm and larger PAH 11.3 μm/7.7 μm band ratios. Although the current data are highly restrictive, they suggest that these anomalous PAH band ratios cannot be explained by the effects of the AGN radiation field alone. Instead, they hint that small grains may be destroyed by the combined effects of radiative processes and shocks, which are plausibly linked to jets and outflows preferentially associated with highly sub-Eddington, radiatively inefficient AGNs. While quasars also present a PAH deficit and unusual PAH band ratios, their characteristics differ in detail compared to those observed in more weakly accreting AGNs, a possible indicator of fundamental differences in their modes of energy feedback.

We combine mid-infrared diagnostics obtained from integral-field-unit observations taken with Mid-Infrared Instrument/Medium Resolution Spectrograph on the James Webb Space Telescope with cold molecular gas information derived from Atacama Large Millimeter/submillimeter Array observations of CO(1–0) emission to investigate the star formation rate and efficiency within the central ∼1.5 kpc × 1.3 kpc region of the Seyfert 1 galaxy NGC 7469 on ∼100 pc scales. The active nucleus leaves a notable imprint on its immediate surroundings by elevating the temperature of the warm molecular gas, driving an ionized gas outflow on subkiloparsec scales, and selectively destroying small dust grains. These effects, nevertheless, have relatively little impact on the cold circumnuclear medium or its ability to form stars. Most of the star formation in NGC 7469 is confined to a clumpy starburst ring, but the star formation efficiency remains quite elevated even for the nuclear region that is most affected by the active nucleus.