The Trigonodus Dolomit is the dolomitized portion of the homoclinal ramp sediments of the Middle Triassic Upper Muschelkalk in the south‐east Central European Basin. Various dolomitizing mechanisms, followed by recrystallization, have been previously invoked to explain the low δ18O, high 87Sr/86Sr, extensive spatial distribution and early nature of the replacive matrix dolomites. This study re‐evaluates the origin, timing and characteristics of the dolomitizing fluids by examining petrographic and isotopic trends in the Trigonodus Dolomit at 11 boreholes in northern Switzerland. In each borehole the ca 30 m thick unit displays the same vertical trends with increasing depth: crystal size increase, change from anhedral to euhedral textures, ultraviolet‐fluorescence decrease, δ18OVPDB decrease from −1·0‰ at the top to −6·7‰ at the base and an 87Sr/86Sr increase from 0·7080 at the top to 0·7117 at the base. Thus, dolomites at the top of the unit record isotopic values similar to Middle Triassic seawater (δ18OVSMOW = 0‰; 87Sr/86Sr = 0·70775) while dolomites at the base record values similar to meteoric groundwaters from the nearby Vindelician High (δ18OVSMOW = −4·0‰; 87Sr/86Sr = >0·712). According to water–rock interaction modelling, a single dolomitizing or recrystallizing fluid cannot have produced the observed isotopic trends. Instead, the combined isotopic, geochemical and petrographic data can be explained by dolomitization via seepage‐reflux of hypersaline brines into dense, horizontally‐advecting groundwaters that already had negative δ18O and high 87Sr/86Sr values. Evidence for the early groundwaters is found in meteoric calcite cements that preceded dolomitization and in fully recrystallized dolomites with isotopic characteristics identical to the groundwaters following matrix dolomitization. This study demonstrates that early groundwaters can play a decisive role in the formation and recrystallization of massive dolomites and that the isotopic and textural signatures of pre‐existing groundwaters can be preserved during seepage‐reflux dolomitization in low‐angle carbonate ramps.

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The Middle-Jurassic Opalinus Clay is the foreseen host rock for radioactive waste disposal in central northern Switzerland. An extensive drilling campaign aiming to characterize the argillaceous formation resulted in a comprehensive drill core data set. The rheologically weak Opalinus Clay is only mildly deformed compared to the over- and underlying rock units but shows a variety of natural fractures. While these structures are hydraulically indistinguishable from macroscopically non-deformed Opalinus Clay today, their analysis allows for a better understanding of the deformation behaviour in the geological past. Here, we present an overview of the different fracture and fault types recorded in the Opalinus Clay and a detailed microstructural characterization of veins—natural dilational fractures healed by secondary calcite and celestite mineralizations. Macroscopic drill core analysis revealed five different natural fracture types that encompass tension gashes of various orientations with respect to bedding and small-scale faults with displacements typically not exceeding the drill core diameter. The occurrence of different fault types generally fits well with the local tectonic setting of the different drilling sites and with respect to the neighbouring regional fault zones. The microstructural investigations of the various vein types revealed their often polyphase character. Fibrous bedding-parallel veins of presumable early age were found to be overprinted by secondary slickenfibres. The polyphase nature of fibrous bedding parallel veins and slickenfibres is supported by differing elemental compositions, pointing towards repeated fracturing and mineralization events. Direct dating of vein calcites with U–Pb was unsuccessful. Nevertheless, age constraints can be inferred from structural orientations and fault slip kinematics. Accordingly, some of the veins already formed during sediment compaction in Mesozoic times, others possibly relate to Early Cenozoic foreland uplift. The youngest veins are most likely related to Late Cenozoic regional tectonic events, such as the Jura fold-and-thrust belt to the south and the Hegau-Lake Constance Graben to the northeast of the study area. During these latest tectonic events, previously formed veins acted as rheologically stiff discontinuities in the otherwise comparably weak Opalinus Clay along which deformation of the rock formation was re-localized.

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Creation of secondary dissolution porosity in carbonate rocks during deep burial has the potential to improve reservoir properties for hydrocarbons, gas storage, and geothermal applications. However, the occurrence and mechanisms of such porosity enhancement are controversial. Here, we present compelling evidence for generation of deep burial porosity from the Swiss Molasse Basin, where dissolution of eogenetic anhydrite nodules in dolostones of the Middle Triassic Muschelkalk increased the matrix porosity by up to 15 vol.%. We reconstruct the genesis and evolution of the anhydrite-dissolution porosity based on petrography, porosity determinations, analyses of stable and radiogenic isotopes (δ2H, δ18O, δ34S, and 87Sr/86Sr), fluid inclusion studies, and laser U–Pb geochronology of secondary calcite. The results show that modified meteoric waters derived from the Variscan crystalline basement ascended via basement–cover cross-formational faults into the overlying Muschelkalk, where they dissolved the anhydrite nodules throughout an area of at least 55 km2 at 700–2300 m depth and 40–160°C. Secondary calcite in anhydrite moulds yields Late Eocene to Middle Miocene U–Pb ages, which coincide with the timing of basement uplift in the foreland bulge of the Swiss Alpine Orogen. This uplift provided the hydraulic gradients to drive meteoric water deep into the adjacent Molasse basin. Similar enhancement of reservoir properties can be expected in dolostones in other foreland basins that are bordered by a foreland bulge in which fractured basement rocks are exhumed.

<p>The low permeability and excellent sealing properties of mudstones places such sedimentary rocks into focus of geo-engineering applications using clay formations as natural barriers for contaminant transport. Here we investigate microscale deformation structures in the Opalinus Clay in northern Switzerland, which is currently under investigation as a host rock for radioactive waste confinement. We aim to characterize paleo-faulting/fracturing as well as subsequent mineralization events. For this purpose, drill core samples were investigated macroscopically, as well as by low and high-resolution optical light microscopy and scanning electron microscopy (SEM) in combination with energy-dispersive X-ray spectroscopy (EDX). These data were combined with high-resolution trace element maps obtained by Synchrotron X-ray Fluorescence Microscopy (SXFM). By combining the observed microstructures with the micro-chemistry of the associated mineralization events we yield a grouping between different processes and, in combination with cross-cutting relationships, a relative timing of the different deformation events.</p><p>Commonly the Opalinus Clay is weakly deformed, with only few localized deformation structures. The latter include: calcite veins (mm thickness) as well as mineralized (calcite and celestite) thrusts, normal faults and strike-slip faults (all cm thickness). Micro-textural analysis shows that low-angle thrust faults with calcite slickensides on their dip-slip surfaces localize on pre-existing horizontal fibrous calcite veins. The horizontal veins imply an early deformation stage with temporarily high pore fluid pressures under sub-horizontal max. principle stresses within the highly anisotropic mudstone. The first order analysis of the major element chemistry between the calcite forming slickensides and the fibrous veins shows significant differences in Mg, Fe and Mn contents. From a fluid-mechanical perspective, this finding implies that generation of fibrous veins during a first fluid event provides the mechanical discontinuity, which is reused during later fluid assisted thrusting.</p><p>The overprinting relationships between fibrous veins and slickensides indicate that deformation/precipitation events occurred in a cyclic fashion. Such information is a key towards the understanding of fluid assisted deformation and mineralization processes in compacted and anisotropic clay formations. On a regional scale, variations in paleo-deformation-mineralization events in the Opalinus Clay imply regional differences likely related to a gradually varying intensity of compressional (thrusting) and extensional (normal faulting) tectonics throughout northern Switzerland.</p>

<p><span>Clay-rich rocks have very low hydraulic permeability and they also have good chemical retention properties for cationic contaminants. This makes them ideal as host rocks for the underground disposal of radioactive waste. In Switzerland, the Opalinus Clay Formation, Jurassic sediments deposited ~174 Ma ago, is envisaged as potential host rock. A large drilling campaign has recently been run in three potential siting regions in northern Switzerland. Drill core samples from a ~400 m thick Mesozoic low permeability zone were obtained at high spatial resolution in one slanted and eight vertical boreholes. Data including various natural tracers were obtained from these core samples. Here we report on the profiles of the stable isotopes </span><span>δ</span><sup><span>18</span></sup><span>O and </span><span>δ</span><sup><span>2</span></sup><span>H in porewater and groundwater in the eight vertical boreholes. The distribution of the tracers results from hydrogeological and transport processes acting in the past, and the profiles can be interpreted as results of ‘experiments performed by nature’. </span>Hydrogeochemical investigations of groundwater and veins mineralisations help to constrain the temporal evolution of the system <span>and to assess the system’s large-scale transport properties</span>. <span>The comparably large number of boreholes allows us comparing the observed depth distributions of the two tracers not only vertically, but also laterally in the three regions (~15-20 kilometers apart), and in the 2 to 4 boreholes in each region (a few kilometers apart). </span>The isotope profiles from the different boreholes<span> show many similarities, but also distinct features that are mainly related to the lateral variation in aquifer properties. The regional aquifers in the Malm (one locality Hauptrogenstein) and Muschelkalk typically build the upper and lower boundary, respectively, of the </span><span>δ</span><sup><span>18</span></sup><span>O and </span><span>δ</span><sup><span>2</span></sup><span>H profiles. In some, but not in all tracer profiles, there are indications of a local Keuper aquifer in the lower part. The variability reflects the lithological heterogeneity of this rock unit in the lateral dimension. The maximum isotope values plot to the right of the GMWL, are often similar and are found in the central part of the profiles in the Opalinus Clay Formation. Towards the Keuper aquifer (if present), the values decrease and approach the GMWL, and often some gentle decrease is also observed towards the upper aquifer, without reaching the GMWL. Towards the Muschelkalk aquifer, the values decrease sharply and reach the GMWL. The shapes of the profiles hint to the importance of diffusive transport processes over large spatial and geologic time scales. With transport simulations, we try to narrow down the timing of any changes in the aquifer signatures in the more recent past (10 ka to few Ma ago), as well as to assess the importance of various transport mechanisms in the development of the profiles. The interpretation of such tracer profiles </span><span>is a key element with respect to the assessment of the large-scale transport properties of a host rock.</span></p>