The development of new solar-to-fuel scenarios is of great importance, but the construction of molecular systems that convert sunlight into chemical energy represents a challenge. One specific issue is that the molecular systems have to be able to accumulate redox equivalents to mediate the photodriven transformation of relevant small molecules, which mostly involves the orchestrated transfer of multiple electrons and protons. Disulfide/ dithiol interconversions are prominent 2e − /2H + couples and can play an important role for redox control and charge storage. With this background in mind, a new photosensitizer [Ru( S−S bpy)-(bpy) 2 ] 2+ (1 2+ ) equipped with a disulfide functionalized bpy ligand ( S−S bpy, bpy = 2,2′-bipyridine) was synthesized and has been comprehensively studied, including structural characterization by X-ray diffraction. In-depth electrochemical studies show that the S−S bpy ligand in 1 2+ can be reduced twice at moderate potentials (around −1.1 V vs Fc +/0 ), and simulation of the cyclic voltammetry (CV) traces revealed potential inversion (E 2 > E 1 ) and allowed to derive kinetic parameters for the sequential electron-transfer processes. However, reduction at room temperature also triggers the ejection of one sulfur atom from 1 2+ , leading to the formation of [Ru( S bpy)(bpy) 2 ] 2+ (2 2+ ). This chemical reaction can be suppressed by decreasing the temperature from 298 to 248 K. Compared to the archetypical photosensitizer [Ru(bpy) 3 ] 2+ , 1 2+ features an additional low energy optical excitation in the MLCT region, originating from charge transfer from the metal center to the S−S bpy ligand (aka MSCT) according to time-dependent density functional theory (TD-DFT) calculations. Analysis of the excited states of 1 2+ on the basis of ground-state Wigner sampling and using charge-transfer descriptors has shown that bpy modification with a peripheral disulfide moiety leads to an energy splitting between charge-transfer excitations to the S−S bpy and the bpy ligands, offering the possibility of selective charge transfer from the metal to either type of ligands. Compound 1 2+ is photostable and shows an emission from a 3 MLCT state in deoxygenated acetonitrile with a lifetime of 109 ns. This work demonstrates a rationally designed system that enables future studies of photoinduced multielectron, multiproton PCET chemistry.

Ruthenium(II) polypyridine complexes are among the most popular sensitizers in photocatalysis, but they face some severe limitations concerning accessible excited-state energies and photostability that could hamper future applications. In this study, the borylation of heteroleptic ruthenium(II) cyanide complexes with α-diimine ancillary ligands is identified as a useful concept to elevate the energies of photoactive metal-to-ligand charge-transfer (MLCT) states and to obtain unusually photorobust compounds suitable for thermodynamically challenging energy transfer catalysis as well as oxidative and reductive photoredox catalysis. B(C 6 F 5 ) 3 groups attached to the CN – ligands stabilize the metal-based t 2g -like orbitals by ∼0.8 eV, leading to high 3 MLCT energies (up to 2.50 eV) that are more typical for cyclometalated iridium(III) complexes. Through variation of their α-diimine ligands, nonradiative excited-state relaxation pathways involving higher-lying metal-centered states can be controlled, and their luminescence quantum yields and MLCT lifetimes can be optimized. These combined properties make the respective isocyanoborato complexes amenable to photochemical reactions for which common ruthenium(II)-based sensitizers are unsuited, due to a lack of sufficient triplet energy or excited-state redox power. Specifically, this includes photoisomerization reactions, sensitization of nickel-catalyzed cross-couplings, pinacol couplings, and oxidative decarboxylative C–C couplings. Our work is relevant in the greater context of tailoring photoactive coordination compounds to current challenges in synthetic photochemistry and solar energy conversion.

Cyclometalated Ir(III) complexes are often chosen as catalysts for challenging photoredox and triplet−triplet-energy-transfer (TTET) catalyzed reactions, and they are of interest for upconversion into the ultraviolet spectral range. However, the triplet energies of commonly employed Ir(III) photosensitizers are typically limited to values around 2.5−2.75 eV. Here, we report on a new Ir(III) luminophore, with an unusually high triplet energy near 3.0 eV owing to the modification of a previously reported Ir(III) complex with isocyanoborato ligands. Compared to a nonborylated cyanido precursor complex, the introduction of B(C 6 F 5 ) 3 units in the second coordination sphere results in substantially improved photophysical properties, in particular a high luminescence quantum yield (0.87) and a long excited-state lifetime (13.0 μs), in addition to the high triplet energy. These favorable properties (including good long-term photostability) facilitate exceptionally challenging organic triplet photoreactions and (sensitized) triplet−triplet annihilation upconversion to a fluorescent singlet excited state beyond 4 eV, unusually deep in the ultraviolet region. The new Ir(III) complex photocatalyzes a sigmatropic shift and [2 + 2] cycloaddition reactions that are unattainable with common transition metalbased photosensitizers. In the presence of a sacrificial electron donor, it furthermore is applicable to demanding photoreductions, including dehalogenations, detosylations, and the degradation of a lignin model substrate. Our study demonstrates how rational ligand design of transition-metal complexes (including underexplored second coordination sphere effects) can be used to enhance their photophysical properties and thereby broaden their application potential in solar energy conversion and synthetic photochemistry.

Second coordination sphere interactions of cyanido complexes with hydrogen-bonding solvents and Lewis acids are known to influence their electronic structures, whereby the non-labile attachment of B­(C6F5)3 resulted in several particularly interesting new compounds lately. Here, we investigate the effects of borylation on the properties of two FeII cyanido complexes in a systematic manner by comparing five different compounds and using a range of experimental techniques. Electrochemical measurements indicate that borylation entails a stabilization of the FeII-based t2g-like orbitals by up to 1.65 eV, and this finding was confirmed by Mössbauer spectroscopy. This change in the electronic structure has a profound impact on the UV–vis absorption properties of the borylated complexes compared to the non-borylated ones, shifting their metal-to-ligand charge transfer (MLCT) absorption bands over a wide range. Ultrafast UV–vis transient absorption spectroscopy provides insight into how borylation affects the excited-state dynamics. The lowest metal-centered (MC) excited states become shorter-lived in the borylated complexes compared to their cyanido analogues by a factor of ∼10, possibly due to changes in outer-sphere reorganization energies associated with their decay to the electronic ground state as a result of B­(C6F5)3 attachment at the cyanido N lone pair.

A new class of macrocycles denoted as “xanthene­[n]­arenes” was synthesized. In contrast to most other macrocycles, they feature a conformationally restricted bowl shape due to the attached alkyl groups at the linking methylene units. This facilitates the synthesis of cavitands and the self-assembly to molecular capsules via noncovalent interactions. The derivatization potential of the novel macrocycles was demonstrated on the xanthene[3]­arene scaffold. Besides a deep cavitand and an oxygen-embedded zigzag hydrocarbon belt[12]­arene, a modified macrocycle was synthesized that self-assembles into a hydrogen-bonded tetrameric capsule, demonstrating the potential of xanthene­[n]­arenes as a new set of macrocyclic building blocks.

Molecular systems combining light harvesting and charge storage are receiving great attention in the context of, for example, artificial photosynthesis and solar fuel generation. As part of ongoing efforts to develop new concepts for photoinduced proton-coupled electron transfer (PCET) reactivities, we report a cyclometallated iridium(III) complex [Ir(ppy) 2 ( S−S bpy)](PF 6 ) ([1]PF 6 ) equipped with our previously developed sulfurated bipyridine ligand S−S bpy. A new one-step synthetic protocol for S−S bpy is developed, starting from commercially available 2,2′bipyridine, which significantly facilitates the use of this ligand. [1] + features a two-electron reduction with potential inversion (|E 1 | > | E 2 |) at moderate potentials (E 1 = −1.12, E 2 = −1.11 V versus. Fc +/0 at 253 K), leading to a dithiolate species [1] − . Protonation with weak acids allows for determination of pK a = 23.5 in MeCN for the S−H•••S − unit of [1H]. The driving forces for both the H atom and the hydride transfer are calculated to be ∼60 kcal mol −1 and verified experimentally by reaction with a suitable H atom and a hydride acceptor, demonstrating the ability of [1] + to serve as a versatile PCET reagent, albeit with limited thermal stability. In MeCN solution, an orange emission for [1]PF 6 from a triplet-excited state was found. Density functional calculations and ultrafast absorption spectroscopy are used to give insight into the excited-state dynamics of the complex and suggest a significantly stretched S−S bond for the lowest triplet-state T 1 . The structural responsiveness of the disulfide unit is proposed to open an effective relaxation channel toward the ground state, explaining the unexpectedly short lifetime of [1] + . These insights as well as the quantitative ground-state thermochemistry data provide valuable information for the use of S−S bpy-functionalized complexes and their disulfide-/dithiol-directed PCET reactivity.

The activation of N2, CO2 or H2O to energy‐rich products relies on multi‐electron transfer reactions, and consequently it seems desirable to understand the basics of light‐driven accumulation of multiple redox equivalents. Most of the previously reported molecular acceptors merely allow the storage of up to two electrons. We report on a terphenyl compound including two disulfide bridges, which undergoes four‐electron reduction in two separate electrochemical steps, aided by a combination of potential compression and inversion. Under visible‐light irradiation using the organic super‐electron donor tetrakis(dimethylamino)ethylene, a cascade of light‐induced reaction steps is observed, leading to the cleavage of both disulfide bonds. Whereas one of them undergoes extrusion of sulfur to result in a thiophene, the other disulfide is converted to a dithiolate. These insights seem relevant to enhance the current fundamental understanding of photochemical energy storage.