We report on the analysis of nonlinear current-voltage characteristics exhibited by a set of blocking metal/SnO(2)/metal. Schottky barrier heights in both interfaces were independently extracted and their dependence on the metal work function was analyzed. The disorder-induced interface states effectively pinned the Fermi level at the SnO(2) surface, leading to the observed Schottky barriers. The model is useful for any two-terminal device which cannot be described by a conventional diode configuration.
This study aimed to synthesize a composite material composed of bio-based, porous carbon matrix and Cu nanoparticles through a simple, low-cost, and environmentally friendly method. Concentrated Kraft black liquor was used as a carbon precursor, and Cu nanoparticles were homogeneously deposited on the carbon matrix using electrochemical deposition. The textural properties determined using N 2 isotherms indicated increased surface area of a carbon matrix with a micro-mesoporous structure. Voltammetric tests demonstrated that the composite exhibited catalytic properties for electrochemical CO 2 reduction. Compared to the bio-based, porous carbon sample (C matrix), the bio-based carbon electrode electrochemically decorated with Cu nanoparticles (C-Cu composite) exhibited increased current values of approximately 2.4 times, a potential shift of approximately 90 mV, and an onset potential of −1.02 V, under CO 2 saturation.
In this work, we studied metal/SnO2 junctions using transport properties. Parameters such as barrier height, ideality factor and series resistance were estimated at different temperatures. Schottky barrier height showed a small deviation of the theoretical value mainly because the barrier was considered fixed as described by ideal thermionic emission-diffusion model. These deviations have been explained by assuming the presence of barrier height inhomogeneities. Such assumption can also explain the high ideality factor as well as the Schottky barrier height and ideality factor dependence on temperature.
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