Fullerenes (C60, C70) detected in planetary nebulae and carbonaceous chondrites have been implicated to play a key role in the astrochemical evolution of the interstellar medium. However, the formation mechanism...
Since the observation of the first sulfur-containing molecule, carbon monosulfide (CS), in the interstellar medium (ISM) half a century ago, sulfur-bearing species have attracted great attention from the astrochemistry, astrobiology, and planetary geology communities. Nevertheless, it is still not clear in which forms most of the sulfur resides in molecular clouds, an unsolved problem referred to as "sulfur depletion". Reported herein is the formation of thioformic acid (HCOSH)�the simplest thioacid�in interstellar ice analogues containing carbon monoxide (CO) and hydrogen sulfide (H 2 S) at 5 K. Utilizing single photoionization reflectron timeof-flight mass spectrometry and isotopically labeled molecules, thioformic acid molecules were selectively photoionized in the temperature-programmed desorption phase. These studies unravel a key reaction pathway to thioformic acid, an organic molecule recently detected toward the giant molecular cloud G+0.693−0.027 and the hot core G31.41+0.31, thus shedding light on interstellar sulfur chemistry.
Nanobowls represent vital molecular building blocks of end-capped nanotubes and fullerenes detected in combustion systems and in deep space such as toward the planetary nebula TC-1, but their fundamental formation mechanisms have remained elusive. By merging molecular beam experiments with electronic structure calculations, we reveal a complex chain of reactions initiated through the gas-phase preparation of benzocorannulene (C24H12) via ring annulation of the corannulenyl radical (C20H9•) by vinylacetylene (C4H4) as identified isomer-selectively in situ via photoionization efficiency curves and photoion mass-selected threshold photoelectron spectra. In silico studies provided compelling evidence that the benzannulation mechanism can be expanded to pentabenzocorannulene (C40H20) followed by successive cyclodehydrogenation to the C40 nanobowl (C40H10) – a fundamental building block of buckminsterfullerene (C60). This high-temperature pathway opens up isomer-selective routes to nanobowls via resonantly stabilized free-radical intermediates and ring annulation in circumstellar envelopes of carbon stars and planetary nebulae as their descendants eventually altering our insights of the complex chemistry of carbon in our Galaxy.
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