The internal layers of neutron stars are expected to contain several superfluid components that can significantly affect their dynamics. The description of such objects should rely on hydrodynamic models in which it is possible to unambiguously assign the value of the thermodynamic variables from microscopic calculations of the properties of matter. In this work we consider the phenomenological approach to multifluids modelling championed by Carter and, studying the relaxation of the system towards equilibrium, we assign a precise thermodynamic interpretation to its variables. We show that in thermodynamic equilibrium the equation of state contains less state variables than those needed in the phenomenological model, implying the existence of a gauge freedom of the theory that can be used to simplify the hydrodynamic formulation in the non-dissipative limit. Once this is understood, it becomes easy to translate the different multifluid formalisms that have been proposed in the literature into Carter's form. Finally, we show that the usual concepts of affinity and reaction coordinates, as they are introduced in chemistry, are not affected by the presence of superfluid currents. In an effort to make the concepts clear, the formalism is developed step-by-step from first principles, providing model examples and several applications of practical relevance for the study of superfluid neutron star interiors.
The approach of extended irreversible thermodynamics consists of promoting the dissipative fluxes to non-equilibrium thermodynamic variables. In a relativistic context, this naturally leads to the formulation of the theory of Israel and Stewart (1979), which is, to date, one of the most successful theories for relativistic dissipation. Although the generality of the principle makes it applicable to any dissipative fluid, a connection of the Israel–Stewart theory with microphysics has been established, through kinetic theory, only for the case of ideal quantum gases. By performing a convenient change of variables, we provide, for the case of bulk viscosity, an equivalent reformulation of the equations at the basis of extended irreversible thermodynamics. This approach maps any thermodynamic process which contributes to the bulk viscosity into a set of chemical reactions, whose reaction coordinates are abstract parameters describing the displacement from local thermodynamic equilibrium of the fluid element. We apply our new formalism to the case of the relativistic fluids, showing that the Israel–Stewart model for bulk viscosity is just the second-order expansion of a minimal model belonging to a larger class of non-perturbative theories for bulk viscosity which include the nuclear-reaction-mediated bulk viscosity of neutron star matter as a particular case. Furthermore, we show with concrete examples that our formalism provides new ways of computing the bulk viscosity directly and defines a simple prescription for constructing the Israel–Stewart model for a generic bulk-viscous fluid.
In a relativistic context, the main purpose of Extended Irreversible Thermodynamics (EIT) is to generalize the principles of non-equilibrium thermodynamics to the domain of fluid dynamics. In particular, the theory aims at modeling any diffusion-type process (like heat as diffusion of energy, viscosity as diffusion of momentum, charge-conductivity as diffusion of particles) directly from thermodynamic laws. Although in Newtonian physics this task can be achieved with a first-order approach to dissipation (i.e. Navier–Stokes–Fourier like equations), in a relativistic framework the relativity of simultaneity poses serious challenges to the first-order methodology, originating instabilities which are, instead, naturally eliminated within EIT. The first part of this work is dedicated to reviewing the most recent progress made in understanding the mathematical origin of this instability problem. In the second part, we present the formalism that arises by promoting non-equilibrium thermodynamics to a classical effective field theory. We call this approach Unified Extended Irreversible Thermodynamics (UEIT), because it contains, as particular cases, EIT itself, in particular the Israel-Stewart theory and the divergence-type theories, plus Carter’s approach and most branches of non-equilibrium thermodynamics, such as relativistic chemistry and radiation hydrodynamics. We use this formalism to explain why all these theories are stable by construction (provided that the microscopic input is correct), showing that their (Lyapunov) stability is a direct consequence of the second law of thermodynamics.
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