Ultrathin c-Si solar cells have the potential to drastically reduce costs by saving raw material while maintaining good efficiencies thanks to the excellent quality of monocrystalline silicon. However, efficient light trapping strategies must be implemented to achieve high short-circuit currents. We report on the fabrication of both planar and patterned ultrathin c-Si solar cells on glass using low temperature (T < 275 °C), low-cost, and scalable techniques. Epitaxial c-Si layers are grown by PECVD at 160 °C and transferred on a glass substrate by anodic bonding and mechanical cleavage. A silver back mirror is combined with a front texturation based on an inverted nanopyramid array fabricated by nanoimprint lithography and wet etching. We demonstrate a short-circuit current density of 25.3 mA/cm(2) for an equivalent thickness of only 2.75 μm. External quantum efficiency (EQE) measurements are in very good agreement with FDTD simulations. We infer an optical path enhancement of 10 in the long wavelength range. A simple propagation model reveals that the low photon escape probability of 25% is the key factor in the light trapping mechanism. The main limitations of our current technology and the potential efficiencies achievable with contact optimization are discussed.
Intense 1.54 m fluorescence of Er 3 + / Yb 3 + codoped phosphate glass and the three-photon phenomenon of near infrared upconversion luminescence Physical characteristics and infrared fluorescence properties of sol-gel derived Er 3+ -Yb 3+ codoped TiO 2We have studied the temperature dependence of the visible fluorescence lines of 250 nm large PbF 2 nanocrystals codoped with Er 3+ and Yb 3+ ions. By gluing such a particle at the end of a sharp atomic force microscope tip, we have developed a scanning thermal microscope able to observe the heating of electrically excited micro-and nanowires. By modulating the electrical current that flows in the structure, the resulting temperature variations modulate the particle fluorescence giving rise to the thermal contrast. We will show that the fluorescence is affected both by the near-field optical distribution and by temperature variations. We will show that it is possible to get rid of these optical effects and to keep the thermal contribution by comparing the images to reference images obtained when the device is not driven by a current. The determination of the temperature of the devices is performed by analyzing the thermal quenching of the fluorescent particle and is in good agreement with numerical simulations. The spatial resolution is in the range of the fluorescent particle size ͑smaller than 500 nm͒, and the temperature sensitivity is smaller than 5 K.
We report here the direct observation by using a scanning near-field microscopy technique of the light focusing through a photonic crystal flat lens designed and fabricated to operate at optical frequencies. The lens is fabricated using a III-V semiconductor slab, and we directly visualize the propagation of the electromagnetic waves by using a scanning near-field optical microscope. We directly evidence spatially, as well as spectrally, the focusing operating regime of the lens. At last, in light of the experimental scanning near-field optical microscope pictures, we discuss the lens ability to focus light at a subwavelength scale.
A 2-D photonic crystal was integrated experimentally into a thin-film crystalline-silicon solar cell of 1-µm thickness, after numerical optimization maximizing light absorption in the active material.The photonic crystal boosted the short-circuit current of the cell, but it also damaged its opencircuit voltage and fill factor, which led to an overall decrease in performances. Comparisons between modeled and actual optical behaviors of the cell, and between ideal and actual morphologies, show the global robustness of the nanostructure to experimental deviations, but its particular sensitivity to the conformality of the top coatings and the spread in pattern dimensions, which should not be neglected in the optical model. As for the electrical behavior, the measured internal quantum efficiency shows the strong parasitic absorptions from the transparent conductive oxide and from the back-reflector, as well as the negative impact of the nanopattern on surface passivation. Our exemplifying case, thus, illustrates and experimentally confirms two recommendations for future integration of surface nanostructures for light trapping purposes: 1) the necessity to optimize absorption not for the total stack but for the single active material, and 2) the necessity to avoid damage to the active material by pattern etching.
Light localization due to random imperfections in periodic media is paramount in photonics research. The group index is known to be a key parameter for localization near photonic band edges, since small group velocities reinforce light interaction with imperfections. Here, we show that the size of the smallest localized mode that is formed at the band edge of a one-dimensional periodic medium is driven instead by the effective photon mass, i.e. the flatness of the dispersion curve. Our theoretical prediction is supported by numerical simulations, which reveal that photonic-crystal waveguides can exhibit surprisingly small localized modes, much smaller than those observed in Bragg stacks thanks to their larger effective photon mass. This possibility is demonstrated experimentally with a photonic-crystal waveguide fabricated without any intentional disorder, for which near-field measurements allow us to distinctly observe a wavelength-scale localized mode despite the smallness (~1/1000 of a wavelength) of the fabrication imperfections.
We study here the lateral evanescent coupling between photonic crystals cavities. The structure consists in two identical monomode Fabry–Perot nanocavities, integrated on silicon-on-insulator slot-waveguides (WG). Spectral and optical near field measurements were led and supported quantitatively by three dimensional simulations. It appears that this system produces a bimodal response: two resonances corresponding, respectively, to an even and odd mode. Particularly, the even case exhibits a field localization in the air slot inferior to λair/10. We demonstrate that merging a slotted WG structure with state-of-the-art nanocavities is a significant step toward an efficient air-slotted resonator.
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