Tianjin, located in Bohai Bay, China, constitutes a relevant study area to investigate emerging per- and polyfluoroalkyl substances (PFASs) due to its high population density, clustering of chemical and aircraft industries, as well as international airports, harbors, and oil rigs. In this study, 53 anionic, zwitterionic, and cationic PFASs were monitored in river surface water, groundwater, seawater, and sediments in this area (overall n = 226). 6:2 chlorinated polyfluorinated ether sulfonic acid (Cl-PFESA), perfluorooctanoic acid, and perfluorooctane sulfonic acid were generally the predominant PFASs. 6:2 fluorotelomer sulfonamidoalkyl betaine (6:2 FTAB) was also widespread (occurrence >86%), with the highest concentration (1300 ng/L) detected at contamination hot spots impacted by wastewater effluents. The aqueous film-forming foam (AFFF)-related PFASs with sulfonamide betaine, amine oxide, amine, or quaternary ammonium moieties are also reported for the first time in river water and seawater samples. Fifteen classes of infrequently reported PFASs, including n:2 FTABs and n:2 fluorotelomer sulfonamide amines, hydrogen-substituted PFESA homologues, and p-perfluorous nonenoxybenzenesulfonate (OBS), were also identified in the water and sediment samples using suspect screening. Field-derived sediment–water distribution coefficients (K d) of these emerging PFASs are provided for the first time, confirming that cationic and zwitterionic PFASs tend to be strongly associated with sediments.

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Construction of subway line intersection stations will become more and more popular in the future. Research on the deformation characteristics in the construction process is the best way to ensure the safety of the foundation pit itself, the surrounding buildings, and adjacent subway stations. In this paper, the deformation characteristics of a T-shaped subway foundation pit during construction are studied by an integrated dewatering-excavation three-dimensional numerical simulation method. The results show that the main causation of the surface settlement around the foundation pit is the stratum compression caused by dewatering, and the main causation of the deformation of the diaphragm wall and the existing subway station is the soil deformation caused by excavation unloading. It is suggested that constructing a high-quality diaphragm wall, controlling the water level within the excavation foundation pit, strengthening the monitoring, and timely cement pouring of the bottom plate are key countermeasures to reduce the deformation. The research results of this paper have reference significance for similar projects.