Covalent organic frameworks (COFs), with large surface area, tunable porosity, and lightweight, have gained increasing attention in the electrochemical energy storage realms. In recent years, the development of high‐performance COF‐based electrodes has, in turn, inspired the innovation of synthetic methods, selection of linkages, and design of the topological structures. This review aims to present an overview of the recent advances in designing COF materials for various energy storage technologies. The fundamentals of COF materials, including synthetic chemistry, linkage diversity, and structure design, are first introduced. An in‐depth understanding of the charge storage mechanism and the structure‐property relationships of the COF electrodes is subsequently provided, highlighting their designing strategies in the latest energy storage applications. The last section of this review discusses the challenges COFs are facing and outlines new directions that could advance COF research in emerging energy technologies.

Natural or native molecular hydrogen (H2) can be a major component in natural gas, and yet its role in the global energy sector’s usage as a clean energy carrier is not normally considered. Here, we update the scarce reporting of hydrogen in Australian natural gas with new compositional and isotopic analyses of H2 undertaken at Geoscience Australia. The dataset involves ~1000 natural gas samples from 470 wells in both sedimentary and non-sedimentary basins with reservoir rocks ranging in age from the Neoarchean to Cenozoic. Pathways to H2 formation can involve either organic matter intermediates and its association with biogenic natural gas or chemical synthesis and its presence in abiogenic natural gas. The latter reaction pathway generally leads to H2-rich (>10mol% H2) gas in non-sedimentary rocks. Abiogenic H2 petroleum systems are described within concepts of source–migration–reservoir–seal but exploration approaches are different to biogenic natural gas. Rates of abiogenic H2 generation are governed by the availability of specific rock types and different mineral catalysts, and through chemical reactions and radiolysis of accessible water. Hydrogen can be differently trapped compared to hydrocarbon gases; for example, pore space can be created in fractured basement during abiogenic reactions, and clay minerals and evaporites can act as effective adsorbents, traps and seals. Underground storage of H2 within evaporites (specifically halite) and in depleted petroleum reservoirs will also have a role to play in the commercial exploitation of H2. Estimated H2 production rates mainly from water radiolysis in mafic–ultramafic and granitic rocks and serpentinisation of ultramafic–mafic rocks gives a H2 inferred resource potential between ~1.6 and ~58MMm3 year−1 for onshore Australia down to a depth of 1km. The prediction and subsequent identification of subsurface H2 that can be exploited remains enigmatic and awaits robust exploration guidelines and targeted drilling for proof of concept.

Although studies of transition metal sulfides (TMS) as anode materials for sodium‐ion batteries are extensively reported, the short cycle life is still a thorny problem that impedes their practical application. In this work, a new capacity fading mechanism of the TMS electrodes is demonstrated; that is, the parasitic reaction between electrolyte anions (i.e., ClO4−) and metal sulfides yields non‐conductive and unstable solid‐electrolyte interphase (SEI) and meanwhile, corrosively turns metal sulfides into less‐active oxides. This knowledge guides the development of an electrochemical strategy to manipulate the anion decomposition and construct a stable interface that prevents extensive parasitic reactions. It is shown that introducing sodium nitrate to the electrolyte radically changes the Na+ solvation structure by populating nitrate ions in the first solvation sheath, generating a stable and conductive SEI layer containing both Na3N and NaF. The optimized interface enables an iron sulfide anode to stably cycle for over 2000 cycles with negligible capacity loss, and a similar enhancement in cycle performance is demonstrated on a number of other metal sulfides. This work discloses metal sulfides’ cycling failure mechanism from a unique perspective and highlights the critical importance of manipulating the interface chemistry in sodium‐ion batteries.

The Neoproterozoic–Paleozoic Officer Basin, located in South Australia and Western Australia, remains a frontier basin for energy exploration, with significant uncertainty due to a paucity of data. As part of Geoscience Australia’s Exploring for the Future (EFTF) program, the objective of this study is to derive the petrophysical properties and to characterise potential reservoirs in the Neoproterozoic–Cambrian sedimentary succession in the Officer Basin through laboratory testing and well log interpretation using both conventional and neural network methods. Laboratory measurements of 41 legacy core samples provide the relationships between gas permeability, Klinkenberg corrected permeability, and nano-scale permeability, as well as grain density, effective and total porosity for various rock types. Conventional log interpretation generates the volume fraction of shale, effective and total porosity from gamma ray and lithology logs. A self-organising map (SOM) was used to cluster the well log data to generate petrophysical group/class index and probability profiles for different classes. Neural network technology was employed to approximate porosity and permeability from logs, conventional interpretation results and class index from SOM modelling. The Neoproterozoic−Cambrian successions have the potential to host both conventional and tight hydrocarbon reservoirs. Neoproterozoic successions are demonstrated to host mainly tight reservoirs with the range in average porosity and geometric mean permeability of 4.77–6.39% and 0.00087–0.01307 mD, respectively, in the different sequences. The range in average porosity and geometric mean permeability of the potential Cambrian conventional reservoirs is 14.54−26.38% and 0.341−103.68 mD, respectively. The Neoproterozoic shales have favourable sealing capacities. This work updates the knowledge of rock properties to further the evaluation of the resource potential of the Officer Basin.

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