A nitrogen-doped CoP nanoarray over 3D porous Co foam is proposed as a robust bifunctional catalyst for the hydrogen evolution reaction and oxygen evolution reaction in the overall water-splitting reaction.
Developing alternatives to Pt catalysts is a prerequisite to cost-effectively produce hydrogen. Herein, we demonstrate Ru P nanoparticles (without any doping and modifications) as a highly efficient Pt-like catalyst for the hydrogen evolution reaction (HER) in different pH electrolytes. On transferring the hexagonal close-packed crystal structure of Ru to the orthorhombic structure of Ru P, a greatly improved catalytic activity and stability toward HER is found owing to Ru-P coordination. The electronic state change originates from the P-Ru bonding structures, which accounts for the HER activity improvement compared with Ru nanoparticles. Specifically, Ru P nanoparticles can drive 10 mA cm at a very low overpotential of 55 mV, only 8 mV more than Pt/C in an acidic solution; and an extremely low overpotential of approximately 50 mV is needed in alkaline solution, about 20 mV less than the Pt/C catalyst. The Volmer-Tafel mechanism is indicated on Ru P nanoparticles with the typical Tafel slope of 30 mV dec of Pt metal indicating a Pt-like catalytic ability. Ru P is more active in the Ru-P family as H atoms prefer to adsorb on Ru atoms rather than on the P element according to theoretical calculations. Considering the low price of Ru (20 % of Pt), anti-corrosion ability in the electrolyte, and the safe and reliable fabrication approach, the powder Ru P nanoparticles make an excellent HER catalyst with great promise for large-scale water electrolysis applications.
The results suggest the existence of vaginopathic C. albicans strains with enhanced virulence and tropism for the vagina and the high possibility of sexual transmission of genital C. albicans infection. Identification of specific genotypes that correlate with severity of VVC is also of diagnostic and therapeutic significance.
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