Ring-opening copolymerization of lactide/lactide derivatives and trans-limonene oxide is used for the synthesis of sustainable block copolymers. The method alters the properties of bio-based, non-food-based poly(limonene carbonate).
Poly(limonene carbonate) (PLimC) has a huge potential as a sustainable
biobased polymer due to its promising property profile and the availability
of the raw materials from nonedible resources, i.e., limonene from
orange peel. PLimC and related terpene-based polycarbonates have not
been processed from the melt state successfully due to their comparably
low decomposition temperatures. Indeed, melt-processed PLimC samples
are brittle and colorized. To change the paradigm, we have investigated
compounds of PLimC with biobased ethyl oleate (EtOL). The glass transition
temperature (T
g) and melt viscosity of
these compounds can be readily controlled by the EtOL content. The
melt-processed PLimC/EtOL compounds showed improved mechanical properties
without significant loss in optical properties as compared to neat
PLimC. Interestingly, the PLimC/EtOL compounds could be melt-processed
a second time without significant loss of mechanical and optical properties,
which could mark an important step toward recyclability.
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