Platinum is the most used electrocatalyst in proton exchange
membrane
fuel cells (PEMFCs). Nonetheless, it suffers from various types of
degradation. Identical location electron microscopy has previously
been used to observe local catalyst changes under accelerated stress
tests (ASTs), giving insight into how individual catalyst particles
degrade. However, it is important that such studies are carried out
under relevant reaction conditions, as these can differ substantially
between liquid half-cells and real PEMFC conditions. In this work,
a single cell PEMFC was used to study the degradation of a commercial
Pt-catalyzed membrane electrode assembly by performing square wave
voltage ASTs in a potential range of 0.6 to 1.0 V. Identical location
scanning electron microscopy (IL-SEM) was used to follow the degradation
of the cathodic catalytic layer (CL) throughout 14,000 AST cycles.
From the IL-SEM, we can conclude that the Pt nanoparticles degrade
via Ostwald ripening, crystal migration, and coalescence. Small Pt
nanoparticles agglomerate to larger particles or dissolve and redeposit
to more stable particles, increasing the average particle size during
the ASTs. In addition, cross-sectional TEM images show thinning of
the ionomer layer during the AST procedure. The IL-SEM technique facilitates
observation of local degradation of the CL in real PEMFCs, which will
help to understand different degradation mechanisms, allowing for
better solutions to be designed.
Platinum (Pt) is a widely used electrocatalyst material in fuel cells and electrolysers. Proton exchange membrane (PEM) fuel cells and electrolysis operate under highly acidic conditions whereas the more recently developed anion exchange membrane (AEM) processes take place under alkaline conditions. Pt dissolution and Pt oxidation during operation and varying potentials has been studied mainly for the acidic PEM and less for the alkaline AEM. This study presents a comparison of Pt dissolution and Pt oxidation in 0.5 M H2SO4 and 1 M KOH using electrochemical quartz crystal microbalance (EQCM) on Pt thin films. Physical characterisation using electron microscopy and atomic force microscopy (AFM) revealed small, yet significant differences in the Pt film surface structure, which is related to differences in measured electrochemical surface area (ECSA). The mass increase from adsorption of oxygenated species and Pt oxidation is higher in alkaline conditions compared to in acid while dissolution of Pt is similar.
In situ electrochemical quartz crystal microbalance (E-QCM) provides new insight into enhanced activity of palladium supported on ceria (Pd/CeO2) in hydrogen oxidation reaction.
Platinum (Pt) is a widely used electrocatalyst material in fuel cells and electrolysers. Proton exchange membrane (PEM) fuel cells and electrolysis operate under highly acidic conditions whereas the more recently developed anion exchange membrane (AEM) processes take place under alkaline conditions. Pt dissolution and Pt oxidation during operation and varying potentials has been studied mainly for the acidic PEM and less for the alkaline AEM. This study presents a comparison of Pt dissolution and Pt oxidation in 0.5 M H 2 SO 4 and 1 M KOH using electrochemical quartz crystal microbalance (EQCM) on Pt thin films. Physical characterisation using electron microscopy and atomic force microscopy (AFM) revealed small, yet significant differences in the Pt film surface structure, which is related to differences in measured electrochemical surface area (ECSA). The mass increase from adsorption of oxygenated species and Pt oxidation is higher in alkaline conditions compared to in acid while dissolution of Pt is similar.
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