Hollow structures with an efficient light harvesting and tunable interior component offer great advantages for constructing a Z-scheme system. Controlled design of hollow cobalt sulfide (Co S ) cubes embedded with cadmium sulfide quantum dots (QDs) is described, using hollow Co(OH) as the template and a one-pot hydrothermal strategy. The hollow CdS/Co S cubes utilize multiple reflections of light in the cubic structure to achieve enhanced photocatalytic activity. Importantly, the photoexcited charge carriers can be effectively separated by the construction of a redox-mediator-free Z-scheme system. The hydrogen evolution rate over hollow CdS/Co S is 134 and 9.1 times higher than that of pure hollow Co S and CdS QDs under simulated solar light irradiation, respectively. Moreover, this is the first report describing construction of a hollow Co S based Z-scheme system for photocatalytic water splitting, which gives full play to the advantages of light-harvesting and charges separation.

Hollow structures with an efficient light harvesting and tunable interior component offer great advantages for constructing a Z‐scheme system. Controlled design of hollow cobalt sulfide (Co9S8) cubes embedded with cadmium sulfide quantum dots (QDs) is described, using hollow Co(OH)2 as the template and a one‐pot hydrothermal strategy. The hollow CdS/Co9S8 cubes utilize multiple reflections of light in the cubic structure to achieve enhanced photocatalytic activity. Importantly, the photoexcited charge carriers can be effectively separated by the construction of a redox‐mediator‐free Z‐scheme system. The hydrogen evolution rate over hollow CdS/Co9S8 is 134 and 9.1 times higher than that of pure hollow Co9S8 and CdS QDs under simulated solar light irradiation, respectively. Moreover, this is the first report describing construction of a hollow Co9S8 based Z‐scheme system for photocatalytic water splitting, which gives full play to the advantages of light‐harvesting and charges separation.

Silver cyanamide nanoparticle decorated carbon nitride nanosheets are synthesized to build up a type-II semiconductor heterojunction for visible-light-driven photocatalysis.