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Direct growth of 100 mm long, semiconducting triple‐walled carbon nanotubes (TWNTs) on Si substrates by chemical vapor depoistion is reported. By tailoring the temperature for a certain gas flow rate, a yield of nearly 90% of centimeter‐long TWNTs is obtained. The TWNTs show an unprecedented structural homogeneity, in which each shell maintains a constant chiral index extending over a very large distance (>60 mm). The semiconducting TWNTs can be directly fabricated into field‐effect transistors.

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To study the dispersity of different amine-graphene oxide (amine-GO) in polymer matrix and the interfacial interactions between functionalized graphene oxide and matrix, two kinds of modifiers-organoamine-and aminosilane-coupling agents-were used to functionalize graphene nanosheets to obtain functionalized graphene oxide/waterborne polyurethane nanocomposites by in situ polymerization. The chemical structure, morphology, and interlayer space of amine-GO nanoplatelets were confirmed by FT-IR, Raman, TGA, XPS, TEM, AFM, and XRD. The dispersity behaviors between different amineGOs and polymers were evaluated by FESEM. The thermal, mechanical, and hydrophobic properties of the nanocomposites were investigated by TGA, tensile testing machine, and water contact angle test, respectively. It was found that the tensile strength of nanocomposites was increased from 10.13 to 27.79 and 28.96 Mpa after the addition of amine-GO functionalized by APTMS and APTES, respectively. The better thermal stability and hydrophobicity of nanocomposites were also achieved by the addition of amine-GO, especially those modified by aminosilane-coupling agents. This study paves a new route for designing and developing chemically converted graphene oxide nanosheets/polymer nanocomposite materials by altering suitable amine-modifier to functionalize graphene oxide nanosheets and then optimizing the interphases between graphene oxide nanosheets and polymer matrices.