This work presents ground-based spectrally resolved water emission at R = 30,000–100,000 over infrared wavelengths covered by the JWST (2.9–12.8 μm). Two new surveys with iSHELL and the VISIR are combined with previous spectra from the CRIRES to cover parts of multiple rovibrational and rotational bands observable within telluric transmission bands, for a total of ≈160 spectra and 85 disks (30 of which are JWST targets in Cycle 1). The general expectation of a range of regions and excitation conditions traced by infrared water spectra is for the first time supported by the combined kinematics and excitation as spectrally resolved at multiple wavelengths. The main findings from this analysis are: (1) water lines are progressively narrower from the rovibrational bands at 2–9 μm to the rotational lines at 12 μm, and partly match broad and narrow emission components, respectively, as extracted from rovibrational CO spectra; (2) rotation diagrams of resolved water lines from upper-level energies of 4000–9500 K show vertical spread and curvatures indicative of optically thick emission (≈1018 cm−2) from a range of excitation temperatures (≈800–1100 K); and (3) the new 5 μm spectra demonstrate that slab model fits to the rotational lines at >10 μm strongly overpredict the rovibrational emission bands at <9 μm, implying vibrational excitation not in thermodynamic equilibrium. We discuss these findings in the context of emission from a disk surface and a molecular inner disk wind, and provide a list of guidelines to support the analysis of spectrally unresolved JWST spectra.

EX Lup is a low-mass pre-main-sequence star that occasionally shows accretion-related outbursts. Here, we present JWST/MIRI medium-resolution spectroscopy obtained for EX Lup 14 yr after its powerful outburst. EX Lup is now in quiescence and displays a Class II spectrum. We detect a forest of emission lines from molecules previously identified in infrared spectra of classical T Tauri disks: H2O, OH, H2, HCN, C2H2, and CO2. The detection of organic molecules demonstrates that they are back after disappearing during the large outburst. Spectral lines from water and OH are for the first time deblended and will provide a much-improved characterization of their distribution and density in the inner disk. The spectrum also shows broad emission bands from warm, submicron-size amorphous silicate grains at 10 and 18 μm. During the outburst, in 2008, crystalline forsterite grains were annealed in the inner disk within 1 au, but their spectral signatures in the 10 μm silicate band later disappeared. With JWST we rediscovered these crystals via their 19.0, 20.0, and 23.5 μm emission, the strength of which implies that the particles are at ∼3 au from the star. This suggests that crystalline grains formed in 2008 were transported outwards and now approach the water snowline, where they may be incorporated into planetesimals. Containing several key tracers of planetesimal and planet formation, EX Lup is an ideal laboratory to study the effects of variable luminosity on the planet-forming material and may provide an explanation for the observed high crystalline fraction in solar system comets.

This work presents water emission spectra at wavelengths covered by JWST (2.9-12.8 µm) as spectrally-resolved with high resolving powers (R = 30,000-100,000) using ground-based spectrographs. Two new surveys with iSHELL and VISIR are combined with previous spectra from CRIRES and TEXES to cover parts of multiple ro-vibrational and rotational bands observable within telluric transmission bands, for a total of 85 disks and ≈ 160 spectra. The general expectation of a range of regions and excitation conditions traced by infrared water spectra is for the first time supported by the combined kinematics and excitation as spectrally resolved at multiple wavelengths. The main findings from this analysis are: 1) water lines are progressively narrower going from the ro-vibrational bands at 2-9 µm to the rotational lines at 12 µm, and partly match a broad (BC) and narrow (NC) emission components, respectively, as extracted from ro-vibrational CO spectra; 2) rotation diagrams of resolved water lines from upper level energies of 4000-9500 K show curvatures indicative of optically thick emission (≈ 10 18 cm −2 ) from a range of excitation temperatures (≈ 800-1100 K); 3) the new 5 µm spectra demonstrate that slab model fits to the rotational lines at > 10 µm strongly over-predict the ro-vibrational emission bands at < 9 µm, implying non-LTE excitation. We discuss these findings in the context of a emission from a disk surface and a molecular inner disk wind, and provide a list of detailed guidelines to support the analysis and interpretation of spectrally-unresolved JWST spectra.

EX Lup is a low-mass pre-main sequence star that occasionally shows accretion-related outbursts. Here, we present JWST/MIRI medium resolution spectroscopy obtained for EX Lup fourteen years after its powerful outburst. EX Lup is now in quiescence and displays a Class II spectrum. We detect a forest of emission lines from molecules previously identified in infrared spectra of classical T Tauri disks: H 2 O, OH, H 2 , HCN, C 2 H 2 , and CO 2 . The detection of organic molecules demonstrates that they are back after disappearing during the large outburst. Spectral lines from water and OH are for the first time de-blended and will provide a much improved characterization of their distribution and density in the inner disk. The spectrum also shows broad emission bands from warm, sub-micron size amorphous silicate grains at 10 and 18 µm. During the outburst, in 2008, crystalline forsterite grains were annealed in the inner disk within 1 au, but their spectral signatures in the 10 µm silicate band later disappeared. With JWST we re-discovered these crystals via their 19.0, 20.0, and 23.5 µm emission, whose strength implies that the particles are at ∼3 au from the star. This suggests that crystalline grains formed in 2008 were transported outwards and now approach the water snowline, where they may be incorporated into planetesimals. Containing several key tracers of planetesimal and planet formation, EX Lup is an ideal laboratory to study the effects of variable luminosity on the planet-forming material and may provide explanation for the observed high crystalline fraction in solar system comets.