No abstract

Metal–organic framework (MOF) materials possess a large specific surface area, high porosity, and atomically dispersed metal active sites, which confer excellent catalytic performance as peroxide (peroxodisulfate (PDS), peroxomonosulfate (PMS), and hydrogen peroxide (H2O2)) activation catalysts. However, the limited electron transfer characteristics and chemical stability of traditional monometallic MOFs restrict their catalytic performance and large-scale application in advanced oxidation reactions. Furthermore, the single-metal active site and uniform charge density distribution of monometallic MOFs result in a fixed activation reaction path of peroxide in the Fenton-like reaction process. To address these limitations, bimetallic MOFs have been developed to improve catalytic activity, stability, and reaction controllability in peroxide activation reactions. Compared with monometallic MOFs, bimetallic MOFs enhance the active site of the material, promote internal electron transfer, and even alter the activation path through the synergistic effect of bimetals. In this review, we systematically summarize the preparation methods of bimetallic MOFs and the mechanism of activating different peroxide systems. Moreover, we discuss the reaction factors that affect the process of peroxide activation. This report aims to expand the understanding of bimetallic MOF synthesis and their catalytic mechanisms in advanced oxidation processes.

No abstract

The generation and accumulation of discarded coal gangue (CG) have severe environmental impacts. CG can adsorb other pollutants in the aquatic environment. However, previous studies have not assessed whether CG can adsorb the emerging contaminant tetracycline hydrochloride (TC). Here, discarded CG taken from a mine was pretreated by crushing, cleaning, and sieving and subsequently applied to the adsorption of TC. The adsorption studies were carried out by batch equilibrium adsorption experiments. Our findings indicated that the adsorption behavior could be accurately described using the quasi-first order kinetic and Langmuir adsorption isotherm models, indicating that monolayer adsorption was the main mechanism mediating the interaction between CG and TC. The adsorption process was classified as a thermodynamic endothermic and spontaneous reaction, which was controlled by chemical and physical adsorption, including electrostatic interaction and cation exchange. The pH of the solution had a great influence on the TC adsorption capacity of GC, with higher adsorption occurring in acidic environments compared to alkaline environments. This was attributed to the changes in CG Zeta potential and TC pKa at different pH conditions. Collectively, our findings demonstrated the potential applicability of discarded CG for the adsorption of TC and provided insights into the adsorption mechanisms.