The pores between spheres provide channels to let electrolyte ions easily reach the reaction sites, while the carbon textile provides easy transportation of electrons. The well-organized spheres with large interfaces create more active sites leading to the efficient insertion–extraction of electrolyte ions into the active material.
MgO is promising for CO2 capture. The effect of precursor source on the porous structure and CO2 adsorption of MgO was investigated. The adsorption performance of MgO could be enhanced through the regulation of precursor source and its morphology.
The spinel phase hierarchical mesoporous NiFe2O4 nanocone forest growing on flexible CT can offer a large number of electrochemically active sites for redox reactions. This architecture provides an ultra large exposed surface for redox reactions, short lengths for electron transfer and clear channels for electrolyte diffusion.
It is important for rehabilitation exoskeletons to move with a spatiotemporal motion patterns that well match the upper-limb joint kinematic characteristics. However, few efforts have been made to manipulate the motion control based on human kinematic synergies. This work analyzed the spatiotemporal kinematic synergies of right arm reaching movement and investigated their potential usage in upper limb assistive exoskeleton motion planning. Ten right-handed subjects were asked to reach 10 target button locations placed on a cardboard in front. The kinematic data of right arm were tracked by a motion capture system. Angular velocities over time for shoulder flexion/extension, shoulder abduction/adduction, shoulder internal/external rotation, and elbow flexion/extension were computed. Principal component analysis (PCA) was used to derive kinematic synergies from the reaching task for each subject. We found that the first four synergies can explain more than 94% of the variance. Moreover, the joint coordination patterns were dynamically regulated over time as the number of kinematic synergy (PC) increased. The synergies with different order played different roles in reaching movement. Our results indicated that the low-order synergies represented the overall trend of motion patterns, while the high-order synergies described the fine motions at specific moving phases. A 4-DoF upper limb assistive exoskeleton was modeled in SolidWorks to simulate assistive exoskeleton movement pattern based on kinematic synergy. An exoskeleton Denavit-Hartenberg (D-H) model was established to estimate the exoskeleton moving pattern in reaching tasks. The results further confirmed that kinematic synergies could be used for exoskeleton motion planning, and different principal components contributed to the motion trajectory and end-point accuracy to some extent. The findings of this study may provide novel but simplified strategies for the development of rehabilitation and assistive robotic systems approximating the motion pattern of natural upper-limb motor function.
Hands-and-knees-crawling is an important motor developmental milestone and a unique window into the development of central nervous system (CNS). Mobility during crawling is regularly used in clinical assessments to identify delays in motor development. However, possible contribution from CNS impairments to motor development delay is still unknown. The aim of this study was to quantify and compare inter-limb muscle synergy and kinematics during crawling among infants at a similar developmental age, however, clinically determined to be typically developing (TD, N = 20) infants, infants at risk of developmental delay (ARDD, N = 33), or infants with confirmed developmental delay (CDD, N = 13). We hypothesized that even though all of the groups are at a similar developmental age, there would be differences in kinematic measures during crawling, and such differences would be associated with CNS impairment as measured by electromyography (EMG) features. Surface EMG of eight arm and leg muscles and the corresponding joint kinematic data were collected while participants crawled on hands and knees at their self-selected velocity. Temporal-spatial parameters and normalized Jerk-Cost (JC) function (i.e., smoothness of movement) were computed from the measured kinematics. The inter-limb muscle synergy and the number of co-activating muscles per synergy were measured using EMGs. We found that the infants with CDD demonstrated higher normalized JC values (less movement smoothness), fewer muscle synergies, and more co-activating muscles per synergy, compared to infants with TD (p < 0.05) and ARDD (p < 0.05). Furthermore, the normalized JC values were correlated (p < 0.05) with the number of co-activation muscles per synergy. Our results suggest a constrained neuromuscular control strategy due to neurological injury in infants with CDD, and such constrain may contribute to the reduced movement smoothness in infant crawling.
The grounding grid is critical to the safety and stability of a power system. Corrosive cracking of the grounding conductor is the main cause of deterioration of grounding grid performance. Existing fault diagnosis methods for grounding grids are limited by the number and distribution of grounding leads, and some of them cannot be used for online detection. This paper proposes a grounding grid detection method based on magnetic source excitation. The measuring device consists of four coils, two horizontal excitation coils, and two vertical receiving coils. The secondary magnetic field signal is extracted from the primary field and the background field by properly positioning the coils, such that the measured signal can reflect the underground media more accurately. The measuring device of the method is portable, the measurement process is contactless with the grounding grid, and it is not limited by the grounding leads. Furthermore, it has a strong anti-interference ability and can realize online detection. It was proven by simulations and experiments that the proposed method has a higher measurement accuracy and stronger anti-interference ability when compared with existing methods. This paper also discusses the influence of various factors such as the number and the location of the breakpoints, the frequency of the excitation source, the soil resistivity, and stratification from the measurement data. It was proven that the method has high precision and a wide application range, and is important for guiding significance and reference value in engineering applications.
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