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Chemical looping processes offer a compelling way for effective and viable carbonaceous fuel conversion into clean energy carriers. The uniqueness of chemical looping processes includes their capability of low cost in situ carbon capture, high efficiency energy conversion scheme, and advanced compatibility with state-of-the-art technologies. Based on the different functions of looping particles, two types of chemical looping technologies and associated processes have been developed. Type I chemical looping systems utilize oxygen carrier particles to perform the reduction-oxidation cycles, while Type II chemical looping systems utilize CO 2 carrier particles to conduct carbonation-calcination cycles. The exergy analysis indicates that the chemical looping strategy has the potential to improve fossil fuel conversion schemes. Chemical looping particle performance and looping reactor engineering are the key drivers to the success of chemical looping process development. In this work, the desired particle characterization and recent progress in mechanism studies are generalized, which is followed by a discussion on the looping reactor design. This perspective also illustrates various chemical looping processes for combustion and gasification applications. It shows that both Type I and Type II looping processes have great potentials for flexible and efficient production of electricity, hydrogen and liquid fuels.

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Diffusion of phenol through a biofilm attached to activated carbon particles was investigated. The biofilm was grown on activated carbon particles in a draft-tube three-phase fluidized-bed bioreactor operating in a fed-batch mode. It was found that phenol did not adsorb on the biofilm and that the diffusion coefficient of phenol within the biofilm varied from 13 to 39% of its corresponding value in water. The diffusion coefficient of phenol within the biofilm was reduced by increasing the biofilm density. An extensive literature review of diffusion of substrates through biofilms indicated that this conclusion could be extended to biofilms grown on flat surfaces, rotating cylinders, and even bioflocs.

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A dynamic volume imaging based on the principle of electrical capacitance tomography (ECT), namely, electrical capacitance volume tomography (ECVT), has been developed in this study. The technique generates, from the measured capacitance, a whole volumetric image of the region enclosed by the geometrically three-dimensional capacitance sensor. This development enables a real-time, 3-D imaging of a moving object or a real-time volume imaging (4-D) to be realized. Moreover, it allows total interrogation of the whole volume within the domain (vessel or conduit) of an arbitrary shape or geometry. The development of the ECVT imaging technique primarily encloses the 3-D capacitance sensor design and the volume image reconstruction technique. The electrical field variation in three-dimensional space forms a basis for volume imaging through different shapes and configurations of ECT sensor electrodes. The image reconstruction scheme is established by implementing the neural-network multicriterion optimization image reconstruction (NN-MOIRT), developed earlier by the authors for the 2-D ECT. The image reconstruction technique is modified by introducing into the algorithm a 3-D sensitivity matrix to replace the 2-D sensitivity matrix in conventional 2-D ECT, and providing additional network constraints including 3-to-2-D image matching function. The additional constraints further enhance the accuracy of the image reconstruction algorithm. The technique has been successfully verified over actual objects in the experimental conditions.Index Terms-3-D ECT, dynamic volume imaging, electrical capacitance volume tomography, Hopfield analog neural network.

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