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Multiresponsive wormlike micelles (WLMs) remain a significant challenge in the construction of smart soft materials based on surfactants. Herein, we report the preparation of a viscoelastic wormlike micellar solution based on a new redox-responsive surfactant, sodium dodecylselanylpropyl sulfate (SDSePS), and commercially available benzyl tertiary amine (BTA) in the presence of CO. In this system, SDSePS can be reversibly switched on (selenide) and off (selenoxide) by a redox reaction, akin to that previously reported for benzylselanyl or phenylselanyl surfactants. By alternately adding HO and NH·HO, WLMs can be reversibly broken and formed because of the transformation of the hydrophilic headgroup of SDSePS, originating from the reversible formation of selenoxide. Moreover, WLMs can also be switched on and off by cyclically bubbling CO and N because of the variation of the binding interaction between SDSePS and BTA, resulting from the reversible protonation of BTA. This interesting and unique multiresponsive behavior makes the current WLMs a potential candidate for smart control of the "sol-gel" transition or substantial thickening of solutions.

An enhanced plastic optical fiber (POF)-based surface plasmon resonance (SPR) sensor is proposed by employing a double-sided polished structure. The sensor is fabricated by polishing two sides of the POF symmetrically along with the fiber axis, and a layer of Au film is deposited on each side of the polished region. The SPR can be excited on both polished surfaces with Au film coating, and the number of light reflections will be increased by using this structure. The simulation and experimental results show that the proposed sensor has an enhanced SPR effect. The visibility and full width at half maximum (FWHM) of spectrum can be improved for the high measured refractive index (RI). A sensitivity of 4284.8 nm/RIU is obtained for the double-sided POF-based SPR sensor when the measured liquid RI is 1.42. The proposed SPR sensor is easy fabrication and low cost, which can provide a larger measurement range and action area to the measured samples, and it has potential application prospects in the oil industry and biochemical sensing fields.