We present the catalog of ∼31500 extragalactic HI line sources detected by the completed ALFALFA survey out to z < 0.06 including both high signal-to-noise ratio (> 6.5) detections and ones of lower quality which coincide in both position and recessional velocity with galaxies of known redshift. We review the observing technique, data reduction pipeline, and catalog construction process, focusing on details of particular relevance to understanding the catalog's compiled parameters. We further describe and make available the digital HI line spectra associated with the catalogued sources. In addition to the extragalactic HI line detections, we report nine confirmed OH megamasers and ten OH megamaser candidates at 0.16 < z < 0.22 whose OH line signals are redshifted into the ALFALFA frequency band. Because of complexities in data collection and processing associated with the use of a feed-horn array on a complex single-dish antenna in the terrestrial radio frequency interference environment, we also present a list of suggestions and caveats for consideration by users of the ALFALFA extragalactic catalog for future scientific investigations.

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Abstract. Nitro-aromatic compounds (NACs), as important contributors to the light absorption by brown carbon, have been widely observed in various ambient atmospheres; however, their formation in the urban atmosphere was little studied. In this work, we report an intensive field study of NACs in summer 2016 at an urban Beijing site, characterized by both high-NOx and anthropogenic VOC dominated conditions. We investigated the factors that influence NAC formation (e.g., NO2, VOC precursors, RH and photolysis) through quantification of eight NACs, along with major components in fine particulate matter, selected volatile organic compounds, and gases. The average total concentration of the quantified NACs was 6.63 ng m−3, higher than those reported in other summertime studies (0.14–6.44 ng m−3). 4-Nitrophenol (4NP, 32.4 %) and 4-nitrocatechol (4NC, 28.5 %) were the top two most abundant NACs, followed by methyl-nitrocatechol (MNC), methyl-nitrophenol (MNP), and dimethyl-nitrophenol (DMNP). The oxidation of toluene and benzene in the presence of NOx was found to be a more dominant source of NACs than primary biomass burning emissions. The NO2 concentration level was found to be an important factor influencing the secondary formation of NACs. A transition from low- to high-NOx regimes coincided with a shift from organic- to inorganic-dominated oxidation products. The transition thresholds were NO2 ∼ 20 ppb for daytime and NO2∼25 ppb for nighttime conditions. Under low-NOx conditions, NACs increased with NO2, while the NO3- concentrations and (NO3-)/NACs ratios were lower, implying organic-dominated products. Under high-NOx conditions, NAC concentrations did not further increase with NO2, while the NO3- concentrations and (NO3-)/NACs ratios showed increasing trends, signaling a shift from organic- to inorganic-dominated products. Nighttime enhancements were observed for 3M4NC and 4M5NC, while daytime enhancements were noted for 4NP, 2M4NP, and DMNP, indicating different formation pathways for these two groups of NACs. Our analysis suggested that the aqueous-phase oxidation was likely the major formation pathway of 4M5NC and 3M5NC, while photo-oxidation of toluene and benzene in the presence of NO2 could be more important for the formation of nitrophenol and its derivatives. Using the (3M4NC+4M5NC) ∕ 4NP ratios as an indicator of the relative contribution of aqueous-phase and gas-phase oxidation pathways to NAC formation, we observed that the relative contribution of aqueous-phase pathways increased at elevated ambient RH and remained constant at RH > 30 %. We also found that the concentrations of VOC precursors (e.g., toluene and benzene) and aerosol surface area acted as important factors in promoting NAC formation, and photolysis as an important loss pathway for nitrophenols.

To take full advantage of sunlight for photomechanical materials, NIR-vis-UV light-responsive actuator films of polymer-dispersed liquid crystal (PDLC)/graphene oxide (GO) nanocomposites were fabricated. The strategy is based on phase transition of LCs from nematic to isotropic phase induced by combination of photochemical and photothermal processes in the PDLC/GO nanocomposites. Upon mechanical stretching of the film, both topological shape change and mesogenic alignment occurred in the separated LC domains, enabling the film to respond to NIR-vis-UV light. The homodispersed GO flakes act as photoabsorbent and nanoscale heat source to transfer NIR or VIS light into thermal energy, heating the film and photothermally inducing phase transition of LC microdomains. By utilizing photochemical phase transition of LCs upon UV-light irradiation, one azobenzene dye was incorporated into the LC domains, endowing the nanocomposite films with UV-responsive property. Moreover, the light-responsive behaviors can be well-controlled by adjusting the elongation ratio upon mechanical treatment. The NIR-vis-UV light-responsive PDLC/GO nanocomposite films exhibit excellent properties of easy fabrication, low-cost, and good film-forming and mechanical features, promising their numerous applications in the field of soft actuators and optomechanical systems driven directly by sunlight.

Compared to that of methylammonium lead iodide perovskite (MAPbI), formamidinium lead iodide perovskite (FAPbI) has a smaller energy band gap and greater potential efficiency. To prevent the transformation of α-FAPbI to δ-FAPbI, preparation of (FA)(MA)PbI was regarded as an effective route. Usually, the planar (FA)(MA)PbI perovskite solar cells are fabricated by a solution process. Herein, we report a low-pressure vapor-assisted solution process (LP-VASP) for the growth of (FA)(MA)PbI perovskite solar cells that features improved electron transportation, uniform morphology, high power conversion efficiency (PCE), and better crystal stability. In LP-VASP, the (FA)(MA)PbI films were formed by the reaction between the PbI film with FAI and MAI vapor in a very simple vacuum oven. LP-VASP is an inexpensive way to batch-process solar cells, avoiding the repeated deposition solution process for PbI films, and the device had a low cost. We demonstrate that, with an increase in the MAI content, the (101) peak position of FAPbI shifts toward the (110) peak position of MAPbI, the (FA)(MA)PbI perovskites are stable, and no decomposition or phase transition is observed after 14 days. The photovoltaic performance was effectively improved by the introduction of MA with the highest efficiency being 16.48% under conditions of 40 wt % MAI. The carrier lifetime of (FA)(MA)PbI perovskite films is approximately three times longer than that of pure FAPbI. Using this process, solar cells with a large area of 1.00 cm were fabricated with the PCE of 8.0%.

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A programmable and biomimetic bilayer actuator enabled by a photo-liquefiable azobenzene derivative.

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