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Despite long‐term efforts for exploring antibacterial agents or drugs, potentiating antibacterial activity and meanwhile minimizing toxicity to the environment remains a challenge. Here, it is experimentally shown that the functionality of reduced graphene oxide (rGO) through copper ions displays selective antibacterial activity that is significantly stronger than that of rGO itself and no toxicity to mammalian cells. Remarkably, this antibacterial activity is two‐orders‐of‐magnitude greater than the activity of its surrounding copper ions. It is demonstrated that rGO is functionalized through the cation–π interaction to massively adsorb copper ions to form a rGO–copper composite and result in an extremely low concentration level of surrounding copper ions (less than ≈0.5 µm). These copper ions on rGO are positively charged and strongly interact with negatively charged bacterial cells to selectively achieve antibacterial activity, while rGO exhibits the functionality to not only actuate rapid delivery of copper ions and massive assembly onto bacterial cells but also result in the valence shift in the copper ions from Cu2+ into Cu+, which greatly enhances the antibacterial activity. Notably, this rGO functionality through cation–π interaction with copper ions can similarly achieve algaecidal activity but does not exert cytotoxicity against neutrally charged mammalian cells.

A high sensitivity D-shaped hole double-cladding fiber temperature sensor based on surface plasmon resonance (SPR) is designed and investigated by a full-vector finite element method. Within the D-shaped hole doublecladding fiber, the hollow D-section is coated with gold film and then injected in a high thermo-optic coefficient liquid to realize the high temperature sensitivity for the fiber SPR temperature sensor. The numerical simulation results show that the peaking loss of the D-shaped hole double-cladding fiber SPR is hugely influenced by the distance between the D-shaped hole and fiber core and by the thickness of the gold film, but the temperature sensitivity is almost insensitive to the above parameters. When the thermo-optic coefficient is −2.8 × 10 −4 ∕°C, the thickness of the gold film is 47 nm, and the distance between the D-shaped hole and fiber core is 5 μm, the temperature sensitivity of the D-shaped hole fiber SPR sensor can reach to −3.635 nm∕°C.

In this paper, we theoretically propose a novel graphene-based hybrid plasmonic waveguide (GHPW) consisting of a low-index rectangle waveguide between a high-index cylindrical dielectric waveguide and the substrate with coated graphene on the surface. The geometric dependence of the mode characteristics on the proposed structure is analyzed in detail, showing that the proposed GHPW has a low loss and consequently a relatively long propagation distance. For TM polarization, highly confined modes guided in the low-index gap region between the graphene and the high-index GaAs and the normalized modal area is as small as 0.0018 (λ/4) at 3 THz. In addition to enabling the building of high-density integration of the proposed structure are examined by analyzing crosstalk in a directional coupler composed of two GHPWs. This structure also exhibits ultra-low crosstalk when a center-to-center separation between adjacent GHPWs is 32μm, which shows great promise for constructing various terahertz integrated devices.