High-purity (98.8%, TiO
2
) rutile nanoparticles
were
successfully synthesized using ilmenite sand as the initial titanium
source. This novel synthesis method was cost-effective and straightforward
due to the absence of the traditional gravity, magnetic, electrostatic
separation, ball milling, and smelting processes. Synthesized TiO
2
nanoparticles were 99% pure. Also, highly corrosive environmentally
hazardous acid leachate generated during the leaching process of ilmenite
sand was effectively converted into a highly efficient visible light
active photocatalyst. The prepared photocatalyst system consists of
anatase-TiO
2
/rutile-TiO
2
/Fe
2
O
3
(TF-800), rutile-TiO
2
/Fe
2
TiO
5
(TFTO-800), and anatase-TiO
2
/Fe
3
O
4
(TF-450) nanocomposites, respectively. The pseudo-second-order adsorption
rate of the TF-800 ternary nanocomposite was 0.126 g mg
–1
min
–1
in dark conditions, and a 0.044 min
–1
visible light initial photodegradation rate was exhibited.
The TFTO-800 binary nanocomposite adsorbed methylene blue (MB) following
pseudo-second-order adsorption (0.224 g mg
–1
min
–1
) in the dark, and the rate constant for photodegradation
of MB in visible light was 0.006 min
–1
. The prepared
TF-450 nanocomposite did not display excellent adsorptive and photocatalytic
performances throughout the experiment period. The synthesized TF-800
and TFTO-800 were able to degrade 93.1 and 49.8% of a 100 mL, 10 ppm
MB dye solution within 180 min, respectively.
Dyes in wastewater are a serious problem that needs to
be resolved.
Adsorption coupled photocatalysis is an innovative technique used
to remove dyes from contaminated water. Novel composites of TiO
2
-Fe
3
C-Fe-Fe
3
O
4
dispersed
on graphitic carbon were fabricated using natural ilmenite sand as
the source of iron and titanium, and sucrose as the carbon source,
which were available at no cost. Synthesized composites were characterized
by X-ray diffractometry (XRD), Raman spectroscopy, transmission electron
microscopy (TEM), scanning electron microscopy (SEM), X-ray photoelectron
spectroscopy (XPS), X-ray fluorescence spectroscopy (XRF), and diffuse
reflectance UV–visible spectroscopy (DRS). Arrangement of nanoribbons
of graphitic carbon with respect to the nanomaterials was observed
in TEM images, revealing the occurrence of catalytic graphitization.
Variations in the intensity ratio (
I
D
/
I
G
),
L
a
and
L
D
, calculated from data obtained from Raman
spectroscopy suggested that the level of graphitization increased
with an increased loading of the catalysts. SEM images show the immobilization
of nanoplate microballs and nanoparticles on the graphitic carbon
matrix. The catalyst surface consists of Fe
3+
and Ti
4+
as the metal species, with V, Mn, and Zr being the main
impurities. According to DRS spectra, the synthesized composites absorb
light in the visible region efficiently. Fabricated composites effectively
adsorb methylene blue via π–π interactions, with
the absorption capacities ranging from 21.18 to 45.87 mg/g. They were
effective in photodegrading methylene blue under sunlight, where the
rate constants varied in the 0.003–0.007 min
–1
range. Photogenerated electrons produced by photocatalysts captured
by graphitic carbon produce O
2
•–
radicals, while holes generate OH
•
radicals, which
effectively degrade methylene blue molecules. TiO
2
-Fe
3
C-Fe-Fe
3
O
4
/graphitic carbon composites
inhibited the growth of
Escherichia coli
(69%) and
Staphylococcus aureus
(92%)
under visible light. Synthesized novel composites using natural materials
comprise an ecofriendly, cost-effective solution to remove dyes, and
they were effective in inhibiting the growth of Gram-negative and
Gram-positive bacteria.
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