Figure 6. Plot of In ((A0-A)/(A-Afi) vs. In [py] for reaction (1).Concentrations are similar to those indicated in Figure 5.
Table III. Equilibrium Constants for CoL+-B Adduct Formationsystem 9 "3^, M"1 (CoL')+-MeIM 1.0 11 ± 3 (CoL')+-py 1.0 2.3 ± 0.4
Shared fleets of fully automated vehicles (SAVs) coupled with real-time ride-sharing to and from transit stations are of interest to cities and nations in delivering more sustainable transportation systems. By providing first-mile last-mile (FMLM) connections to key transit stations, SAVs can replace walk-to-transit, drive-to-transit, and drive-only trips. Using the SUMO (Simulation of Urban MObility) toolkit, this paper examines mode splits, wait times, and other system features by micro-simulating two fleets of SAVs providing an FMLM ride-sharing service to 10% of central Austin’s trip-makers near five light-rail transit stations. These trips either start or end within two geofenced areas (called automated mobility districts [AMDs]), and travel time and wait time feedbacks affect mode choices. With rail service headways of 15 min, and 15 SAVs serving FMLM connections to and from each AMD, simulations predict that 3.7% of the person-trip-making will shift from driving alone to transit use in a 3 mi × 6 mi central Austin area. During a 3-h morning peak, 30 SAVs serve about 10 person-trips each (to or from the stations), with 3.4 min average wait time for SAVs, and an average vehicle occupancy of 0.74 persons (per SAV mile-traveled), as a result of empty SAV driving between riders. Sensitivity analysis of transit headways (from 5 to 20 min) and fleet sizes (from 5 to 20 vehicles in each AMD) shows an increase in FMLM mode share with more frequent transit service and larger fleet size, but total travel time served as the biggest determinant in trip-makers’ mode share.
Accurately predicting network-level traffic conditions has been identified as a critical need for smart and advanced transportation services. In recent decades, machine learning and artificial intelligence have been widely applied for traffic state, including traffic volume prediction. This paper proposes a novel deep learning model, Graph Convolutional Neural Network with Data-driven Graph Filter (GCNN-DDGF), for network-wide multi-step traffic volume prediction. More specifically, the proposed GCNN-DDGF model can automatically capture hidden spatiotemporal correlations between traffic detectors, and its sequence-to-sequence recurrent neural network architecture is able to further utilize temporal dependency from historical traffic flow data for multi-step prediction. The proposed model was tested in a network-wide hourly traffic volume dataset between 1 January 2018 and 30 June 2019 from 150 sensors in the Los Angeles area. Detailed experimental results illustrate that the proposed model outperforms the other five widely used deep learning and machine learning models in terms of computational efficiency and prediction accuracy. For instance, the GCNN-DDGF model improves MAE, MAPE, and RMSE by 25.33%, 20.45%, and 29.20% compared to the state-of-the-art models, such as Diffusion Convolution Recurrent Neural Network (DCRNN), which is widely accepted as a popular and effective deep learning model.
The crystals of the title salt, 6,21-diaza-3,9,18,24-tetraazoniatricyclo[22.2.2.2(11,14)]triaconta-11,13,24,26(1),27,29-hexaene benzene-1,2,4,5-tetracarboxylate(4-) hexahydrate, C(24)H(42)N(6)(4+) x C(10)H(2)O(8)(4-) x 6H(2)O, are formed by the intermolecular interaction of a macrocyclic hexamine with a molecule of C(6)H(2)(COOH)(4) in aqueous solution. Both the cation and the anion are on inversion centres. Hydrogen bonds are formed between the four ammonium cations in the hexamine and the four carboxylate anions in the aromatic acid. Stacks exist along the crystallographic a axis in the solid state. The water molecules also take part in a hydrogen-bonding network which joins these stacks together.
Aiming at the problems of the basic sparrow search algorithm (SSA) in terms of slow convergence speed and the ease of falling into the local optimum, the chaotic mapping strategy, adaptive weighting strategy and t-distribution mutation strategy are introduced to develop a novel adaptive sparrow search algorithm, namely the CWTSSA in this paper. In the proposed CWTSSA, the chaotic mapping strategy is employed to initialize the population in order to enhance the population diversity. The adaptive weighting strategy is applied to balance the capabilities of local mining and global exploration, and improve the convergence speed. An adaptive t-distribution mutation operator is designed, which uses the iteration number t as the degree of freedom parameter of the t-distribution to improve the characteristic of global exploration and local exploration abilities, so as to avoid falling into the local optimum. In order to prove the effectiveness of the CWTSSA, 15 standard test functions and other improved SSAs, differential evolution (DE), particle swarm optimization (PSO), gray wolf optimization (GWO) are selected here. The compared experiment results indicate that the proposed CWTSSA can obtain higher convergence accuracy, faster convergence speed, better diversity and exploration abilities. It provides a new optimization algorithm for solving complex optimization problems.
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