Thermoelectric (TE) materials have the capability of converting heat into electricity, which can improve fuel efficiency, as well as providing robust alternative energy supply in multiple applications by collecting wasted heat, and therefore, assisting in finding new energy solutions. In order to construct high performance TE devices, superior TE materials have to be targeted via various strategies. The development of high performance TE devices can broaden the market of TE application and eventually boost the enthusiasm of TE material research. This review focuses on major novel strategies to achieve high‐performance TE materials and their applications. Manipulating the carrier concentration and band structures of materials are effective in optimizing the electrical transport properties, while nanostructure engineering and defect engineering can greatly reduce the thermal conductivity approaching the amorphous limit. Currently, TE devices are utilized to generate power in remote missions, solar–thermal systems, implantable or/wearable devices, the automotive industry, and many other fields; they are also serving as temperature sensors and controllers or even gas sensors. The future tendency is to synergistically optimize and integrate all the effective factors to further improve the TE performance, so that highly efficient TE materials and devices can be more beneficial to daily lives.
The urgent need for ecofriendly, stable, long‐lifetime power sources is driving the booming market for miniaturized and integrated electronics, including wearable and medical implantable devices. Flexible thermoelectric materials and devices are receiving increasing attention, due to their capability to convert heat into electricity directly by conformably attaching them onto heat sources. Polymer‐based flexible thermoelectric materials are particularly fascinating because of their intrinsic flexibility, affordability, and low toxicity. There are other promising alternatives including inorganic‐based flexible thermoelectrics that have high energy‐conversion efficiency, large power output, and stability at relatively high temperature. Herein, the state‐of‐the‐art in the development of flexible thermoelectric materials and devices is summarized, including exploring the fundamentals behind the performance of flexible thermoelectric materials and devices by relating materials chemistry and physics to properties. By taking insights from carrier and phonon transport, the limitations of high‐performance flexible thermoelectric materials and the underlying mechanisms associated with each optimization strategy are highlighted. Finally, the remaining challenges in flexible thermoelectric materials are discussed in conclusion, and suggestions and a framework to guide future development are provided, which may pave the way for a bright future for flexible thermoelectric devices in the energy market.
As a key type of emerging thermoelectric material, tin telluride (SnTe) has received extensive attention because of its low toxicity and eco-friendly nature. The recent trend shows that band engineering and nanostructuring can enhance thermoelectric performance of SnTe as intermediate temperature (400-800 K) thermoelectrics, which provides an alternative for toxic PbTe with the same operational temperature. This review highlights the key strategies to enhance the thermoelectric performance of SnTe materials through band engineering, carrier concentration optimization, synergistic engineering, and structure design. A fundamental analysis elucidates the underpinnings for the property improvement. This comprehensive review will boost the relevant research with a view to work on further performance enhancement of SnTe materials.where k B , e, h, m*, µ, and L are the Boltzmann constant, the carrier charge, the Planck's constant, the effective mass of the charge carrier, the carrier mobility, and the Lorenz number, respectively. As can be seen, S, σ, and κ e are interacted and conflict, which raises the difficulty to obtain high ZT. To solve these conflicts, extensive research has been carried out through band engineering to optimize S and σ, [5][6][7] and structuring to reduce the κ l . [8][9][10][11][12] Figure 1a summarizes recent significant achievements in different thermoelectric materials including SnSe, [25] 3%Na-(PbTe) 0.8 (PbS) 0.2 , [70] Cu 2 S 0.5 Te 0.5 , [71] and GeSbTe. [72] As can be seen, the current ZT values of the thermoelectric materials lie between 1 and 2, [7,[13][14][15][16][17][18][19][20][21][22][23] resulting in the fact that the current thermoelectric energy conversion efficiency is comparable to the other energy conversion technologies, such as photovoltaic cells, [22] and solar thermal plants. [22] Considerable research has been continuing to further drive ZT higher than 2 with the predicted efficiency over 20%, [24,25] which can attract highly exciting prospect in the energy generation and conservation fields.In terms of the industrial and automotive applications, waste heats are generally produced in the temperature range of 500-900 K. [26][27][28] To recover such waste heats, developing high-performance mid-temperature (400-900 K) thermoelectric materials is highly desired. For this purpose, lead telluride (PbTe) and its alloys have been considered as a primary material system. [7,10,14,17,29] However, the toxicity associated with Pb causes severe threat to the environment and needs to be alternated for domestic usage. [30] Hence, as its analog, tin telluride (SnTe) [21,[30][31][32][33][34][35][36][37][38][39][40][41][42][43][44] with the rock-salt crystal structure has been inspired with great interests. [32] Especially, SnTe is nontoxic, earth-abundant, and environment friendly, [45] which makes it
Driven by the prospective applications of thermoelectric materials, massive efforts have been dedicated to enhancing the conversion efficiency. The latter is governed by the figure of merit (ZT), which is proportional to the power factor (S(2)σ) and inversely proportional to the thermal conductivity (κ). Here, we demonstrate the synthesis of high-quality ternary Bi2Te3-xSex nanoplates using a microwave-assisted surfactant-free solvothermal method. The obtained n-type Bi2Te2.7Se0.3 nanostructures exhibit a high ZT of 1.23 at 480 K measured from the corresponding sintered pellets, in which a remarkably low κ and a shift of peak S(2)σ to high temperature are observed. By detailed electron microscopy investigations, coupled with theoretical analysis on phonon transports, we propose that the achieved κ reduction is attributed to the strong wide-frequency phonon scatterings. The shifting of peak S(2)σ to high temperature is due to the weakened temperature dependent transport properties governed by the synergistic carrier scatterings and the suppressed bipolar effects by enlarging the band gap.
GeTe with rhombohedral-to-cubic phase transition is a promising lead-free thermoelectric candidate. Herein, theoretical studies reveal that cubic GeTe has superior thermoelectric behavior, which is linked to (1) the two valence bands to enhance the electronic transport coefficients and (2) stronger enharmonic phonon-phonon interactions to ensure a lower intrinsic thermal conductivity. Experimentally, based on Ge Sb Te with optimized carrier concentration, a record-high figure-of-merit of 2.3 is achieved via further doping with In, which induces the distortion of the density of states near the Fermi level. Moreover, Sb and In codoping reduces the phase-transition temperature to extend the better thermoelectric behavior of cubic GeTe to low temperature. Additionally, electronic microscopy characterization demonstrates grain boundaries, a high-density of stacking faults, and nanoscale precipitates, which together with the inevitable point defects result in a dramatically decreased thermal conductivity. The fundamental investigation and experimental demonstration provide an important direction for the development of high-performance Pb-free thermoelectric materials.
N-type Bi2Te3 nanostructures were synthesized using a solvothermal method and in turn sintered using sparking plasma sintering. The sintered n-type Bi2Te3 pellets reserved nanosized grains and showed an ultralow lattice thermal conductivity (∼0.2 W m(-1) K(-1)), which benefits from high-density small-angle grain boundaries accommodated by dislocations. Such a high phonon scattering leads an enhanced ZT of 0.88 at 400 K. This study provides an efficient method to enhance thermoelectric performance of thermoelectric nanomaterials through nanostructure engineering, making the as-prepared n-type nanostructured Bi2Te3 as a promising candidate for room-temperature thermoelectric power generation and Peltier cooling.
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