Quantum chemical calculations of the anions AeF- (Ae = Be - Ba) and the isoelectronic group-13 molecules EF (E = B - Tl) have been carried out using ab initio...
The methodology for the synthesis of fluorenebased atropisomers was developed via the strategy of aromatic ring formation. By this strategy, an efficient benzannulation of indenebased diene with benzoylacetonitrile divergently promoted by DABCO and a chiral organocatalyst was established, and various atropisomeric fluorene-based skeletons were generated in good yields, which not only provide a new strategy for the construction of atropisomeric biaryls but also offer a new member to the atropisomeric family.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.