In this work, the structure of composite was designed as Core Stack and Surface Stack, which was treated with the expandable graphite (EG) and metal oxides such as iron oxide (IO), hydroxyapatite (HA), and aluminum tri-hydroxide (ATH). The mechanical performance of composites was characterized via flexural performance and interlaminar shear strength analysis. The flame retardance and smoke suppression of composite was explored in detail by LOI, UL-94, and cone calorimeter test. The findings presented that flexural properties of composites were observed to decrease due to delamination of surface stack, whilst no significant effect on interlaminar shear strength. In comparison with control composite, the loading of metal oxide into composite Surface Stack led to the reduction of peak heat release rate, total heat release, and fire growth index effectively. Moreover, the remarkable decrease in total smoke production could be observed due to the addition of iron oxide and the flame retardant mechanism was discussed. This study was the preliminary exploration of composite with flame retardant design which could be potential solution to improve flame retardancy and smoke suppression of composite with better mechanical structure preservation.
The fire-retardant properties of high-performance fiber-reinforced composites are the crucial benchmark for composite structure stability. However, in the current flame-retardant solution for composites it is difficult to reach the balance between fire resistance and structural performance due to the deteriorating composite interface. In this work, the carbon fiber-reinforced composite was covered with functional glass fiber layers, in which the glass fiber veil had been treated with flame-retardant agents and silicone-modified waterborne polyurethane, in order to be endowed with flame-retardant capability and structure toughness. As such, a significant improvement in the flame retardancy and mechanical structure of the composites could be observed. When compared with the control, the total heat release and total smoke release for composites with 8% silicone-modified waterborne polyurethane treatment could be decreased by 18.5% and 18.1%, while the tensile and flexural strength were significantly increased by 47.3% and 62.2%, respectively. This well-balanced performance is attributable to the structure design with a toughened glass fiber veil to protect the composite surfaces from fire combustion and structure failure. Therefore, this flame-retardant structure design provides a new strategy to achieve high-performance composites with prospective applications for aircraft and aerospace.
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