Novel luminescent "nano-bombs" based on a self-assembled system of carbon-nanodots, termed supra-CDs, are developed. The luminescence of these luminescent "nano-bombs" depends strongly on water contact; they show weak emission in toluene and decompose in contact with water, resulting in strong photoluminescence. Paper coated with these "nano-bombs" is successfully applied for water-jet printing of luminescence patterns and the mapping of human sweat-pore patterns.

Carbon nanofibers grown on the surface of graphite felt by chemical vapour deposition was investigated for the first time in vanadium redox flow batteries. The electrochemical activity and reversibility of the carbon nanofibers modified graphite felt electrode are enhanced. A catalytic mechanism for electrochemical reaction of V(IV)/V(V) couple is proposed.

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Most advanced humidity sensors are powered by batteries that need regular charging and replacement, causing environmental problems and complicated management issues. This paradigm has been overcome through the development of new technology based on the concept of simple, self-powered, rapid-response, flexible humidity sensors enabled by the properties of densely packed titanium dioxide (TiO 2 ) nanowire networks. These sensors eliminate the need for an external power source and produce an output voltage that can be readily related to ambient humidity level over a wide range of ambient conditions. They are characterized by rapid response and relaxation times (typically 4.5 and 2.8 s, respectively). These units are mechanically flexible and maintain a constant voltage output after 10 000 bending cycles. This new type of humidity sensor is easily attached to a human finger for use in the monitoring of ambient humidity level in the environment around human skin, near wet objects, or in the presence of moist materials. The unique properties of this new self-powered wearable humidity sensor technology open up a variety of new applications, including the development of electronic skin, personal healthcare products, and smart tracking in the future Internet-of-things.

Mesozoic contraction deformation in the Yanshan and Taihang mountains is characterized by basement-involved thrust tectonics, basement-cored buckling anticlines and ductile thrust and nappe tectonics. Most of these deformations are orientated west-east, west-northwest and northeast to north-northeast. The contraction deformations began in the Permian, continued through the Triassic and Jurassic and terminated in the Early Cretaceous, and constitute an important part of the destruction of the North China Craton. It is estimated, from balanced cross-section reconstructions, that the north-south shortening of the central part of the Yanshan belt before 135 Ma was around 38%. The initial crust thickness, pre-dating the major contraction deformation in late Paleozoic and early Mesozoic, was estimated to be around 35 km based on paleogeographic characteristics. Assuming that the inferred depth of ductile thrusting deformation, 20-25 km, was the crust thickness involved in the contraction deformation, and also assuming that the N-S contraction deformation was accommodated by vertical crust thickening, the thickness of the crust after the contraction deformation was expected to be around 47-50 km. This was the approximate crust thickness required for the eclogitization of the lower crust for delamination. The gravity potential accumulated by the isostatic uplift of the thickened crust, together with the decrease in crustal strength caused by the coeval magmatisms associated with the contraction deformation, led to the subsequent extensional collapse of the middle and upper crust although the regional stress regime associated with the plate interactions remained constant. It is inferred that the Mesozoic contraction deformations in the Yanshan and Taihang mountains were not only a significant tectonic process contributing to the destruction of the craton in middle and upper crust but also stimulated delamination at a deep level and the extension of the shallow crust. In other words, both the suspected delamination of the lower crust and upper mantle and the well constrained extension deformations of the shallow crust in the eastern North China Craton during the late Mesozoic are a consequence of crust thickening due to previous contractions. Extensional deformations could be expected to occur independently in the shallow crust, and are not necessarily associated with or responding to delamination at a deep level.

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Lithium-rich oxide material has been considered as an attractive candidate for high-energy cathode for lithium-ion batteries (LIBs). However, the practical applications are still hindered due to its low initial reversible capacity, severe voltage decaying, and unsatisfactory rate capability. Among all, the voltage decaying is a serious barrier that results in a large decrease of energy density during long-term cycling. To overcome these issues, herein, an efficient strategy of fabricating lithium-rich oxide nanowires with spinel/layered heterostructure is proposed. Structural characterizations verify that the spinel/layered heterostructured nanowires are a self-assembly of a lot of nanoparticles, and the LiMnO spinel phase is embedded inside the layered structure. When the material is used as cathode of LIBs, the spinel/layered heterostructured nanowires can display an extremely high invertible capacity of 290.1 mA h g at 0.1 C and suppressive voltage fading. Moreover, it exhibits a favorable cycling stability with capacity retention of 94.4% after charging/discharging at 0.5 C for 200 cycles and it shows an extraordinary rate capability (183.9 mA h g, 10 C). The remarkable electrochemical properties can be connected with the spinel/layered heterostructure, which is in favor of Li transport kinetics and enhancing structural stability during the cyclic process.

Enantioselective functionalizations of unbiased methylene C(sp )-H bonds of linear systems by metal insertion are intrinsically challenging and remain a largely unsolved problem. Herein, we report a palladium(II)-catalyzed enantioselective arylation of unbiased methylene β-C(sp )-H bonds enabled by the combination of a strongly coordinating bidentate PIP auxiliary with a monodentate chiral phosphoric acid (CPA). The synergistic effect between the PIP auxiliary and the non-C -symmetric CPA is crucial for effective stereocontrol. A broad range of aliphatic carboxylic acids and aryl bromides can be used, providing β-arylated aliphatic carboxylic acid derivatives in high yields (up to 96 %) with good enantioselectivities (up to 95:5 e.r.). Notably, this reaction also represents the first palladium(II)-catalyzed enantioselective C-H activation with less reactive and cost-effective aryl bromides as the arylating reagents. Mechanistic studies suggest that a single CPA is involved in the stereodetermining C-H palladation step.