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Polyvinyl chloride (PVC) is a widely used polymer, not only in industry, but also in our daily life. PVC is a material that can be applied in many different fields, such as building and construction, health care, and electronics. In recent decades, the success of electrospinning technology to fabricate nanofibers has expanded the applicability of polymers. PVC nanofibers have been successfully manufactured by electrospinning. By changing the initial electrospinning parameters, it is possible to obtain PVC nanofibers with diameters ranging from a few hundreds of nanometers to several micrometers. PVC nanofibers have many advantages, such as high porosity, high mechanical strength, large surface area, waterproof, and no toxicity. PVC nanofibers have been found to be very useful in many fields with a wide variety of applications such as air filtration systems, water treatment, oil spill treatment, batteries technology, protective clothing, corrosion resistance, and many others. This paper reviews the fabricating method, properties, applications, and prospects of PVC nanofibers.

In this work, polyvinyl chloride (PVC)/clay nanofiber composites with various contents were fabricated by the electrospinning process. The morphology, porosity, density, and mechanical properties of the nanofiber mats were investigated. In addition, PVC/clay nanofiber mats were characterized by Fourier transform infrared spectroscopy, differential scanning calorimetry, and thermogravimetric analysis. Moreover, the influence of the clay content in the nanofiber mats and its effect on oil sorption capacity were also evaluated. The results show that the clay particle diameter affects the fabrication, morphology, porosity, density, mechanical properties, and sorption capacity of the nanofiber mats. Adding clay in nanofiber composite materials leads to higher porosity and a higher oil sorption capacity. PVC/clay nanofiber mats have a high oil sorption capacity at low temperatures. They exhibit a high potential to be used as materials to eliminate oil spills under arctic conditions.

The optical properties of the polymer composites consisting of polyvinyl chloride nanofibers and polypropylene films in the frequency range of 0.2–1.0 THz were studied, and the mechanical properties of polyvinyl chloride nanofibers and the structure porosity were investigated. An iterative mathematical model based on effective medium theory was used to describe the effective refractive index and absorption coefficient of the polymer composites. The permittivity tensors of the composites were calculated using the Rytov method. We found that the refractive indices of the composites increased with the increase of polypropylene contents, while absorption coefficients remained the same. The polarization-dependencies of THz optical properties of the composites were relatively low. The proposed composites have the potential to be used as materials for terahertz optical components.

The paper describes the process of obtaining electrospun nanofibers from solutions of polyvinyl chloride in tetrahydrofuran and in a mixture of tetrahydrofuran and dimethylformamide. The regularity of size variation of polyvinyl chloride nanofibers depending on the selected technological parameters was analyzed. The optimal formulation for the preparation of the polymer solution was chosen on the basis of the obtained experimental data. That developed formulation ensures the stability of the electrospinning of nanofibers with desired morphological characteristics. The results of the experiment show that increasing of polyvinyl chloride concentration from 10 to 30 mass. % leads to increasing in the diameter of electrospinning nanofibers based on polyvinyl chloride from 291 nm to 395 nm. The tensile strength and tensile modulus for electrospun nanofiber films based on polyvinyl chloride are 2.21 MPa and 53.2 MPa, respectively.

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