A novel catalytic coating that converts
coke to carbon oxides through
a reaction with steam has been developed. Several coating formulations
were tested in a jet-stirred reactor setup, and the best performing
formulation was further evaluated in a pilot plant setup. Application
of the coating during steam cracking of ethane at industrially relevant
conditions resulted in a reduction of the asymptotic coking rate by
76%. The coating activity remained constant over several coking/decoking
cycles. Coupled furnace-reactor run length simulations of an industrial
ethane cracking unit were performed and resulted in an increase of
the run length by a factor of 6. However, the simulated CO2 yield is higher than the design value of a typical caustic tower.
The title compound 1 can be viewed as trimethylphosphane‐substituted titanocene. 1 provides a readily accessible and simple source of titanocene in solution; the PMe3 ligands can be replaced by a variety of substrates under mild conditions.
Als Trimethylphosphan‐stabilisiertes Titanocen kann die Titelverbindung 1 aufgefaßt werden. Mit 1 ist Titanocen in bisher unerreichter Einfachheit in Lösung zugänglich geworden; die PMe3‐Liganden können unter milden Bedingungen durch eine Vielzahl von Substraten ersetzt werden
.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.