Recent experimental and theoretical studies demonstrate that pressure driven flow of fluids through nanoscale ( d < 10 nm) carbon pores occurs 4 to 5 orders of magnitude faster than predicted by extrapolation from conventional theory. Here, we report experimental results for flow of water, ethanol, and decane through carbon nanopipes with larger inner diameters (43 +/- 3 nm) than previously investigated. We find enhanced transport up to 45 times theoretical predictions. In contrast to previous work, in our systems, decane flows faster than water. These nanopipes were composed of amorphous carbon deposited from ethylene vapor in alumina templates using a single step fabrication process.

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Topological protection is an elegant way of warranting the integrity of quantum and nanosized systems. In magnetism one example is the Bloch-point, a peculiar object implying the local vanishing of magnetization within a ferromagnet. Its existence had been postulated and described theoretically since several decades, however it has never been observed. We confirm experimentally the existence of Bloch points, imaged within domain walls in cylindrical magnetic nanowires, combining surface and transmission XMCD-PEEM magnetic microscopy. This opens the way to the experimental search for peculiar phenomena predicted during the motion of Bloch-point-based domain walls.There is a rising interest for physical systems providing topological protection. The interest is both fundamental to elucidate the underlying physical phenomena, and applied as a mean to provide robustness to a state against external perturbations and decoherence pathways. For example, the peculiar topology of the band structure of carbon nanotubes and graphene forbids backscattering of charge carriers [1], an effect which is often invoked to explain the high mobilities up to room temperature [2]. A similar effect occurs at the surface of so-called topological insulators, together with a locking of the spin of charge carriers; this provides spin currents protected against depolarization [3]. A photonic analogue was also designed by combining helical wave guides on a lattice with a graphene-like honeycomb topology, removing time-reversal symmetry and thereby preventing backscattering of light [4].In systems displaying a directional order parameter such as liquid crystals and ferromagnets, interesting phenomena are associated with the slowly-varying texture of the order field (magnetization for a ferromagnet). The requirement of local continuity of a vector field with fixed magnitude provides a topological protection against the transformation of the texture. A prototypical case in magnetism is skyrmions, which are essentially local two-dimensional chiral spin textures stabilized by the Dzyaloshinskii-Moriya interaction, embedded in an otherwise uniformly-magnetized surrounding. Despite these surroundings skyrmions cannot unwind continuously as explained by the above continuity constraints of the magnetization field, explaining their topological protection. Skyrmions have first been predicted theoretically [5], then confirmed experimentally in both bulk [6] and thin film forms [7].Bloch points are yet another type of topologicallyprotected magnetic texture which cannot be unwound, however of a three-dimensional nature. Bloch points are such that given the distribution of magnetization set on a closed surface like a sphere, the enclosed volume cannot be mapped with a continuous magnetization field of finite magnitude. This occurs e.g. for hedge-hog configurations, or more generally whenever all directions of magnetization are mapped on the closed surface (Fig. 1a-b). Such boundary conditions imply the local cancellation of the modulus of magnetization on a...

An error has been detected in our calculation of slip lengths for the flow of fluids through 44 nm diameter nanopipes which have been corrected in the revised Table 1 below. The main results, namely, the experimentally determined values we report for flow enhancement, and our conclusions are not affected. We express our gratitude to J. Thomas and A. McGaughey from the Department of Mechanical Engineering at Carnegie Mellon University who drew the error to our attention. NL900746G

Arrays of thermoelectric bismuth telluride (Bi(2)Te(3)) nanowires were grown into porous anodic alumina (PAA) membranes prepared by a two-step anodization. Bi(2)Te(3) nanowire arrays were deposited by galvanostatic, potentiostatic and pulsed electrodeposition from aqueous solution at room temperature. Depending on the electrodeposition method and as a consequence of different growth mechanisms, Bi(2)Te(3) nanowires exhibit different types of crystalline microstructure. Bi(2)Te(3) nanowire arrays, especially those grown by pulsed electrodeposition, have a highly oriented crystalline structure and were grown uniformly as compared to those grown by other electrodeposition techniques used. X-ray diffraction (XRD) analyses are indicative of the existence of a preferred growth orientation. High resolution transmission electron microscopy (HRTEM) and selected area electron diffraction (SAED) confirm the formation of a preferred orientation and highly crystalline structure of the grown nanowires. The nanowires were further analyzed by scanning electron microscopy (SEM). Energy dispersive x-ray spectrometry (EDX) indicates that the composition of Bi-Te nanowires can be controlled by the electrodeposition method and the relaxation time in the pulsed electrodeposition approach. The samples fabricated by pulsed electrodeposition were electrically characterized within the temperature range 240 K≤T≤470 K. Below T≈440 K, the nanowire arrays exhibited a semiconducting behavior. Depending on the relaxation time in the pulsed electrodeposition, the semiconductor energy gaps were estimated to be 210-290 meV. At higher temperatures, as a consequence of the enhanced carrier-phonon scattering, the measured electrical resistances increased slightly. The Seebeck coefficient was measured for every Bi(2)Te(3) sample at room temperature by a very simple method. All samples showed a positive value (12-33 µV K(-1)), indicating a p-type semiconductor behavior.

This work investigates the structure and interface perpendicular magnetic anisotropy ͑PMA͒ of electrodeposited Cu/Co/Au͑111͒ sandwiches with variable Co thickness ͓2-20 monolayers ͑ML's͔͒. In optimum deposition conditions, polar magneto-optical Kerr effect measurements show that the axis of easy magnetization is perpendicular to the layers for thicknesses below ca. 7.2 ML's. This value is among the best ever reported for the Cu/Co/Au͑111͒ structure. While extended x-ray-absorption fine structure indicates that layers are hcp, in situ STM imaging suggests that magnetoelastic effects contribute significantly to PMA. The correlation observed between the strength of PMA and film structure is discussed in details.

Stainless Steel / Microstructures / Microfabrication / Electrochemistry / Short Voltage PulsesApplication of ultrashort voltage pulses to a tiny tool electrode under suitable electrochemical conditions enables precise three-dimensional machining of stainless steel. In order to reach submicrometer precision and high processing speed, the formation of a passive layer on the workpiece surface during the machining process has to be prevented by proper choice of the electrolyte. Mixtures of concentrated hydrofluoric and hydrochloric acid are well suited in this respect and allow the automated machining of complicated three-dimensional microelements. The dependence of the machining precision on pulse duration and pulse amplitude was investigated in detail.

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