Coal seam gas production involves generation and management of large amounts of co‐produced water. One of the most suitable methods of management is injection into deep aquifers. Field injection trials may be used to support the predictions of anticipated hydrological and geochemical impacts of injection. The present work employs reactive transport modeling (RTM) for a comprehensive analysis of data collected from a trial where arsenic mobilization was observed. Arsenic sorption behavior was studied through laboratory experiments, accompanied by the development of a surface complexation model (SCM). A field‐scale RTM that incorporated the laboratory‐derived SCM was used to simulate the data collected during the field injection trial and then to predict the long‐term fate of arsenic. We propose a new practical procedure which integrates laboratory and field‐scale models using a Monte Carlo type uncertainty analysis and alleviates a significant proportion of the computational effort required for predictive uncertainty quantification. The results illustrate that both arsenic desorption under alkaline conditions and pyrite oxidation have likely contributed to the arsenic mobilization that was observed during the field trial. The predictive simulations show that arsenic concentrations would likely remain very low if the potential for pyrite oxidation is minimized through complete deoxygenation of the injectant. The proposed modeling and predictive uncertainty quantification method can be implemented for a wide range of groundwater studies that investigate the risks of metal(loid) or radionuclide contamination.
Coal seam gas (CSG) extraction generates large volumes of coproduced water. Injection of the excess water into deep aquifers is often the most sustainable management option. However, such injection risks undesired sediment–water interactions that mobilize metal(loid)s in the receiving aquifer. This risk can be mitigated through pretreatment of the injectant. Here, we conducted a sequence of three push–pull tests (PPTs) where the injectant was pretreated using acid amendment and/or deoxygenation to identify the processes controlling the fate of metal(loid)s and to understand the treatment requirements for large-scale CSG water injection. The injection and recovery cycles were closely monitored, followed by analysis of the observations through reactive transport modeling. While arsenic was mobilized in all three PPTs, significantly lower arsenic concentrations were observed in the recovered water when the injectant was deoxygenated, regardless of pH adjustment. The breakthrough of arsenic was commensurate with molybdenum, but distinct from phosphate. This allowed for the observed and modeled arsenic and molybdenum mobilization to be attributed to a stoichiometric codissolution process during pyrite oxidation, whereas phosphate mobility was governed by sorption. Understanding the nature of these hydrochemical processes explained the greater efficiency of pretreatment by deoxygenation on minimizing metal(loid) mobilization compared to the acid amendment.
The Precipice Sandstone is a major Great Artesian Basin aquifer in the Surat Basin, Queensland, Australia, which is used for water supply and production of oil and gas. This report describes use of observed groundwater pressure responses to managed aquifer recharge (MAR) at a regional scale to test recent geological descriptions of Precipice Sandstone extent, and to inform its hydrogeological conceptualisation. Since 2015, two MAR schemes have injected over 20 GL of treated water from coal seam gas production into the Precipice Sandstone, with pressure responses rapidly propagating over 100 km, indicating high aquifer diffusivity. Groundwater modelling of injection and inversion of pressure signals using PEST software shows the spatial variability of aquifer properties, and indicates that basin in-situ stresses and faulting exert control on permeability. Extremely high permeability, up to 200 m/day, occurs in heavily fractured regions with a dual-porosity flow regime. The broader-scale estimates of permeability approach an order of magnitude higher than previous studies, which has implications for the management of water resources in the Precipice Sandstone. Results also show the Precipice Sandstone to have broadly isotropic permeability. The results also support a recent geological interpretation of the Precipice Sandstone as having more limited lateral extent than initially considered. The study shows the effective use of MAR injection data to improve geological and hydrogeological understanding through groundwater model inversion. It also demonstrates the utility of combining hydrogeological and reservoir-engineer datasets in areas explored and developed for both groundwater resources and oil and gas resources.
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