Sunlight photolysis of uranyl nitrate and uranyl acetate solutions in pyridine produces uranyl peroxide complexes. To answer longstanding questions about the origin of these complexes, we conducted a series of mechanistic studies and demonstrate that these complexes arise from photochemical oxidation of water. The peroxo ligands are easily removed by protonolysis, allowing regeneration of the initial uranyl complexes for potential use in catalysis.
Despite playing a fundamental role in all models of Himalayan tectonics, minimal data constraining the structural evolution, metamorphic history, and offset magnitude of the South Tibetan detachment system (STDS) are available. Here, we integrate petrofabric, finite strain, and kinematic data with metamorphic and deformation temperatures to generate a structural model for the STDS in northwestern Bhutan. We divide the STDS into an ∼2-km-thick lower level that accommodated ∼6–13 km of thinning via ≥30–76 km of simple shear-dominant displacement within Greater Himalayan rocks, and an ∼3-km-thick upper level that accommodated ≥21 km of displacement via an upward decrease (from 44% to 2%) in transport-parallel lengthening within Tethyan Himalayan rocks. Peak metamorphic temperatures in the lower level are ∼650–750 °C, and two distinct intervals of telescoped isotherms in the upper level define a cumulative upward decrease from ∼700 to ∼325 °C. These intervals are separated by an abrupt upward increase from ∼450 to ∼620 °C, which we interpret as the result of post-STDS thrust repetition. Above the upper telescoped interval, temperatures gradually decrease upward from ∼325 to ∼250 °C through a 7-km-thick section of overlying Tethyan Himalayan rocks. Telescoped isotherms lie entirely above the high-strain lower level of the STDS zone, which we attribute to progressive elevation of isotherms during protracted intrusion of granite sills. This study demonstrates the utility of using gradients in fabric intensity and thin section-scale finite strain to delineate shear zone boundaries when field criteria for delineating strain gradients are not apparent.
Graphite Creek is an unusual flake graphite deposit located on the Seward Peninsula, Alaska, USA. We present field observations, uranium-lead (U–Pb) monazite and titanite geochronology, carbon (C) and sulfur (S) stable isotope geochemistry, and graphite Raman spectroscopy data from this deposit that support a new model of flake graphite ore genesis in high-grade metamorphic environments. The Graphite Creek deposit is within the second sillimanite metamorphic zone of the Kigluaik Mountains gneiss dome. Flake graphite, hosted in sillimanite-gneiss and quartz-biotite paragneiss, occurs as disseminations and in sets of very high grade (up to 50 wt.% graphite), semi-massive to massive graphite lenses 0.2 to 1 m wide containing quartz, sillimanite, inclusions of garnet porphyroblasts, K-feldspar, and tourmaline. Restitic garnet, sillimanite, graphite, and biotite accumulations indicate a high degree of anatexis and melt loss. Strong yttrium depletion in monazite, high europium ratios (Eu/Eu*), and excursions of high strontium and thorium concentrations are consistent with biotite dehydration melting. Monazite and titanite U–Pb ages record peak metamorphism from ~ 97 to 92 million years ago (Ma) and a retrograde event at ~ 85 Ma. Raman spectroscopy confirms the presence of carbonaceous material and highly ordered, crystalline graphite. Graphite δ13CVPDB values of − 30 to − 12‰ and pyrrhotite δ34SVCDT values of − 14 to 10‰ are consistent with derivation from organic carbon and sulfur in sedimentary rocks, respectively. These data collectively suggest that formation of massive graphite lenses occurred approximately synchronously with high-temperature metamorphism and anatexis of a highly carbonaceous pelitic protolith. Melt extraction and fluid release associated with anatexis were likely crucial for concentrating graphite. High-temperature, graphitic migmatite sequences within high-strain shear zones may be favorable for the occurrence of high-grade flake graphite deposits.
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