shows a strong bias to 6-membered lactams over the 5-membered analogues, which can be explained by a greater reactivity of the six-membered palladacycles.3
The [Rh(xantphos)]+ fragment acts as an effective catalyst for the hydroboration of the alkene TBE (tert-butyl ethene) using the amine–borane H3B·NMe3 at low (0.5 mol%) catalyst loadings to give the linear product.
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