Compositional mapping has greatly impacted mineralogical and petrological studies over the past half-century with increasing use of the electron probe micro-analyser. Many technical and analytical developments have benefited from the synergies of physicists and geologists and they have greatly contributed to the success of this analytical technique. Large-area compositional mapping has become routine practice in many laboratories worldwide, improving our ability to measure the compositional variability of minerals in natural geological samples and reducing the operator bias as to where to locate single spot analyses. This chapter aims to provide an overview of existing quantitative techniques for the evaluation of rock and mineral compositions and to present various examples of applications. A new advanced method for compositional map standardization that relies on internal standards and accurately corrects the X-ray intensities for continuum background is also presented. This technique has been implemented into the computer software XMapTools. The improved workflow defines the appropriate practice of accurate standardization and provides data-reporting standards to help improve petrological interpretations.

No abstract

No abstract

Linking ages to metamorphic stages in rocks that have experienced low‐ to medium‐grade metamorphism can be particularly tricky due to the rarity of index minerals and the preservation of mineral or compositional relicts. The timing of metamorphism and the Mesozoic exhumation of the metasedimentary units and crystalline basement that form the internal part of the Longmen Shan (eastern Tibet, Sichuan, China), are, for these reasons, still largely unconstrained, but crucial for understanding the regional tectonic evolution of eastern Tibet. In situ core‐rim 40Ar/39Ar biotite and U–Th/Pb allanite data show that amphibolite facies conditions (~10–11 kbar, 530°C to 6–7 kbar, 580°C) were reached at 210–180 Ma and that biotite records crystallization, rather than cooling, ages. These conditions are mainly recorded in the metasedimentary cover. The 40Ar/39Ar ages obtained from matrix muscovite that partially re‐equilibrated during the post peak‐P metamorphic history comprise a mixture of ages between that of early prograde muscovite relicts and the timing of late muscovite recrystallization at c. 140–120 Ma. This event marks a previously poorly documented greenschist facies metamorphic overprint. This latest stage is also recorded in the crystalline basement, and defines the timing of the greenschist overprint (7 ± 1 kbar, 370 ± 35°C). Numerical models of Ar diffusion show that the difference between 40Ar/39Ar biotite and muscovite ages cannot be explained by a slow and protracted cooling in an open system. The model and petrological results rather suggest that biotite and muscovite experienced different Ar retention and resetting histories. The Ar record in mica of the studied low‐ to medium‐grade rocks seems to be mainly controlled by dissolution–reprecipitation processes rather than by diffusive loss, and by different microstructural positions in the sample. Together, our data show that the metasedimentary cover was thickened and cooled independently from the basement prior to c. 140 Ma (with a relatively fast cooling at 4.5 ± 0.5°C/Ma between 185 and 140 Ma). Since the Lower Cretaceous, the metasedimentary cover and the crystalline basement experienced a coherent history during which both were partially exhumed. The Mesozoic history of the Eastern border of the Tibetan plateau is therefore complex and polyphase, and the basement was actively involved at least since the Early Cretaceous, changing our perspective on the contribution of the Cenozoic geology.

The Longmen Shan belt (eastern border of the Tibetan plateau) constitutes a tectonically active region as demonstrated by the occurrence of the unexpected 2008 Mw 7.9 Wenchuan and 2013 Mw 6.6 Lushan earthquakes in the central and southern parts of the belt, respectively. These events revealed the necessity of a better understanding of the long‐term geological evolution of the belt and its effect on the present dynamics and crustal structure. New structural and thermobarometric data offer a comprehensive data set of the paleotemperatures across the belt and P‐T estimates for low‐grade metamorphic domains. In the central Longmen Shan, two metamorphic jumps of 150–200 °C, 5–6 kbar and ~50 °C, 3–5 kbar acquired during the Early Mesozoic are observed across the Wenchuan and Beichuan faults, respectively, attesting to their thrusting movement and unrevealing a major decollement between the allochtonous Songpan‐Garze metasedimentary cover (at T > 500 °C) and the autochtonous units and the basement (T < 400 °C). In the southern Longmen Shan, the only greenschist facies metamorphism is observed both in the basement (360 ± 30 °C, 6 ± 2 kbar) and in the metasedimentary cover (350 ± 30 °C, 3 ± 1 kbar). Peak conditions were reached at ca. 80–60 Ma in the basement and ca. 55–33 Ma in the cover, ca. 50 Ma after the greenschist facies metamorphic overprint observed in the central Longmen Shan (ca. 150–120 Ma). This along‐strike metamorphic segmentation coincides well with the present fault segmentation and reveals that the central and southern Longmen Shan experienced different tectonometamorphic histories since the Mesozoic.

The strength of the lithosphere may be constrained qualitatively by field observations on 19 localized vs distributed modes of deformation and by the mineral assemblages formed during 20 deformation. The internal deformation of the Bielsa basement unit of the Pyrenean Axial zone 21 is investigated through structural, microstructural and thermometric data. In this area, 22 shortening is widely distributed as attested by the folded attitude of the interface between the 23 basement and its sedimentary Triassic cover. Shortening is estimated around 1.7 km (13%) 24 from a regional balanced cross-section and should be considered in pre-Pyrenean 25 reconstructions. Shortening probably occurred before strain localization on crustal ramps as 26 suggested by zircon fission-track analysis. Distributed shortening is characterized at small-27 scale by low-temperature mylonites and cataclasites. In thin-section, feldspar originally 28 present in magmatic rocks is partially to totally sericitized. This transformation led to 29 significant weakening of the rock and took place in the 250-350°C temperature range. 30 Sericitization is ubiquitous, even in un-deformed granodiorites. This shows that the 31 weakening effect of sericitization not only occurs in ultra-mylonites, ultra-cataclasites and 32 2 phyllonites but also more generally in the upper crust early during the shortening history, with 33 implications for the shortening style. Estimates of the geothermal gradient suggest that 34 inherited thermicity may also have influenced the style of shortening. We propose that the 35 upper crust was very weak before or at the onset of its shortening due to high-thermal gradient 36 and fluid circulation that induced large-scale sericitization in greenschist facies conditions. 37 This has strong implications on the rheological evolution of the upper crust submitted to 38 metamorphic alteration in the greenschist facies and below.

No abstract

—Due to its size and high altitude, the growth of the Tibetan Plateau remains an enigma. Based on a synthesis of anterior collisions, paleoaltimetric data, geochemistry of ultrapotassic lava and their rare mantle enclaves, combined with a reinterpretation of tomographic data, we suppose that Tibet’s growth took take place in two main stages. Initially, the accretion of Gondwana terranes to the margin of South Asia, especially during the Early Triassic–Cretaceous period, resulted in the first episode of plateau growth, which affected an area of about 2/3 of the current plateau. We suppose that during the Late Cretaceous, the Tibetan crust reached a thickness of about 50–55 km, which is equivalent to an altitude of about 2500 to 3000 m, with local landforms that could have exceeded 4000 m. Another important consequence of these successive accretions was a strong metasomatism and a softening of the upper part of the Tibetan cover. The P wave low-velocity anomaly currently observed under the central part of Tibet would correspond not to a temperature anomaly but to a composition anomaly. From 50 Ma onwards, the convergence between India and Asia, estimated at about 1000 km on the Tibetan side, led to a shortening of the plateau by about 40%. We suppose that this additional shortening, which has led to the current thickness of the Earth’s crust of about 70 km and an average altitude of 4800 m, has been compensated by the reactivation of the continental slabs along the previous sutures and by the homogeneous shortening of the crust.