[1] Recent progress in sea ice concentration remote sensing by satellite microwave radiometers has been stimulated by two developments: First, the new sensor Advanced Microwave Scanning Radiometer-EOS (AMSR-E) offers spatial resolutions of approximately 6 Â 4 km at 89 GHz, nearly 3 times the resolution of the standard sensor SSM/I at 85 GHz (15 Â 13 km). Second, a new algorithm enables estimation of sea ice concentration from the channels near 90 GHz, despite the enhanced atmospheric influence in these channels. This allows full exploitation of their horizontal resolution, which is up to 4 times finer than that of the channels near 19 and 37 GHz, the frequencies used by the most widespread algorithms for sea ice retrieval, the NASA-Team and Bootstrap algorithms. The ASI algorithm used combines a model for retrieving the sea ice concentration from SSM/I 85-GHz data proposed by Svendsen et al. (1987) with an ocean mask derived from the 18-, 23-, and 37-GHz AMSR-E data using weather filters. During two ship campaigns, the correlation of ASI, NASA-Team 2, and Bootstrap algorithms ice concentrations with bridge observations were 0.80, 0.79, and 0.81, respectively. Systematic differences over the complete AMSR-E period (2002AMSR-E period ( -2006 between ASI and NASA-Team 2 are below À2 ± 8.8%, and between ASI and Bootstrap are 1.7 ± 10.8%. Among the geophysical implications of the ASI algorithm are: (1) Its higher spatial resolution allows better estimation of crucial variables in numerical atmospheric and ocean models, for example, the heat flux between ocean and atmosphere, especially near coastlines and in polynyas. (2) It provides an additional time series of ice area and extent for climate studies.

During springtime in the polar regions, unique photochemistry converts inert halide salt ions (e.g. Br⁻) into reactive halogen species (e.g. Br atoms and BrO) that deplete ozone in the boundary layer to near zero levels. Since their discovery in the late 1980s, research on ozone depletion events (ODEs) has made great advances; however many key processes remain poorly understood. In this article we review the history, chemistry, dependence on environmental conditions, and impacts of ODEs. This research has shown the central role of bromine photochemistry, but how salts are transported from the ocean and are oxidized to become reactive halogen species in the air is still not fully understood. Halogens other than bromine (chlorine and iodine) are also activated through incompletely understood mechanisms that are probably coupled to bromine chemistry. The main consequence of halogen activation is chemical destruction of ozone, which removes the primary precursor of atmospheric oxidation, and generation of reactive halogen atoms/oxides that become the primary oxidizing species. The different reactivity of halogens as compared to OH and ozone has broad impacts on atmospheric chemistry, including near complete removal and deposition of mercury, alteration of oxidation fates for organic gases, and export of bromine into the free troposphere. Recent changes in the climate of the Arctic and state of the Arctic sea ice cover are likely to have strong effects on halogen activation and ODEs; however, more research is needed to make meaningful predictions of these changes

International audienceThe comprehensive isotopic composition of atmospheric nitrate (i.e., the simultaneous measurement of all its stable isotope ratios: 15N/14N, 17O/16O and 18O/16O) has been determined for aerosol samples collected in the marine boundary layer (MBL) over the Atlantic Ocean from 65°S (Weddell Sea) to 79°N (Svalbard), along a ship-borne latitudinal transect. In nonpolar areas, the δ 15N of nitrate mostly deriving from anthropogenically emitted NO x is found to be significantly different (from 0 to 6‰) from nitrate sampled in locations influenced by natural NO x sources (−4 ± 2)‰. The effects on δ 15N(NO3 −) of different NO x sources and nitrate removal processes associated with its atmospheric transport are discussed. Measurements of the oxygen isotope anomaly (Δ17O = δ 17O − 0.52 × δ 18O) of nitrate suggest that nocturnal processes involving the nitrate radical play a major role in terms of NO x sinks. Different Δ17O between aerosol size fractions indicate different proportions between nitrate formation pathways as a function of the size and composition of the particles. Extremely low δ 15N values (down to −40‰) are found in air masses exposed to snow-covered areas, showing that snowpack emissions of NO x from upwind regions can have a significant impact on the local surface budget of reactive nitrogen, in conjunction with interactions with active halogen chemistry. The implications of the results are discussed in light of the potential use of the stable isotopic composition of nitrate to infer atmospherically relevant information from nitrate preserved in ice cores

Abstract. Sea-ice thickness on a global scale is derived from different satellite sensors using independent retrieval methods. Due to the sensor and orbit characteristics, such satellite retrievals differ in spatial and temporal resolution as well as in the sensitivity to certain sea-ice types and thickness ranges. Satellite altimeters, such as CryoSat-2 (CS2), sense the height of the ice surface above the sea level, which can be converted into sea-ice thickness. Relative uncertainties associated with this method are large over thin ice regimes. Another retrieval method is based on the evaluation of surface brightness temperature (TB) in L-band microwave frequencies (1.4 GHz) with a thickness-dependent emission model, as measured by the Soil Moisture and Ocean Salinity (SMOS) satellite. While the radiometer-based method looses sensitivity for thick sea ice (> 1 m), relative uncertainties over thin ice are significantly smaller than for the altimetry-based retrievals. In addition, the SMOS product provides global sea-ice coverage on a daily basis unlike the altimeter data. This study presents the first merged product of complementary weekly Arctic sea-ice thickness data records from the CS2 altimeter and SMOS radiometer. We use two merging approaches: a weighted mean (WM) and an optimal interpolation (OI) scheme. While the weighted mean leaves gaps between CS2 orbits, OI is used to produce weekly Arctic-wide sea-ice thickness fields. The benefit of the data merging is shown by a comparison with airborne electromagnetic (AEM) induction sounding measurements. When compared to airborne thickness data in the Barents Sea, the merged product has a root mean square deviation (RMSD) of about 0.7 m less than the CS2 product and therefore demonstrates the capability to enhance the CS2 product in thin ice regimes. However, in mixed first-year (FYI) and multiyear (MYI) ice regimes as in the Beaufort Sea, the CS2 retrieval shows the lowest bias.

Abstract. During springtime in the polar regions, unique photochemistry converts inert halide salts ions (e.g. Br−) into reactive halogen species (e.g. Br atoms and BrO) that deplete ozone in the boundary layer to near zero levels. Since their discovery in the late 1980s, research on ozone depletion events (ODEs) has made great advances; however many key processes remain poorly understood. In this article we review the history, chemistry, dependence on environmental conditions, and impacts of ODEs. This research has shown the central role of bromine photochemistry, but how salts are transported from the ocean and are oxidized to become reactive halogen species in the air is still not fully understood. Halogens other than bromine (chlorine and iodine) are also activated through incompletely understood mechanisms that are probably coupled to bromine chemistry. The main consequence of halogen activation is chemical destruction of ozone, which removes the primary precursor of atmospheric oxidation, and generation of reactive halogen atoms/oxides that become the primary oxidizing species. The different reactivity of halogens as compared to OH and ozone has broad impacts on atmospheric chemistry, including near complete removal and deposition of mercury, alteration of oxidation fates for organic gases, and export of bromine into the free troposphere. Recent changes in the climate of the Arctic and state of the Arctic sea ice cover are likely to have strong effects on halogen activation and ODEs; however, more research is needed to make meaningful predictions of these changes.