Catalytic enantioselective domino alkenylation-heteroarylation of nonconjugated iododienes proceeded with excellent stereoselectivity and broad scopes of substrates. The reaction enables stereoselective syntheses of substituted azacycles and oxacycles such as piperidine, pyrrolidine,...
A chemoselective (3 + 2) cycloaddition of 2-pyrones and vinyl cyclopropanes for efficient and diastereoselective synthesis of cyclopenta[b]pyran-2-ones.
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