The synthesis of two chiral bulky alkoxide pro-ligands: 1-adamantyl-tert-butylphenylmethanol HOCAdtBuPh and 1-adamantylmethylphenylmethanol HOCAdMePh, and their coordination chemistry with magnesium(II) is described, and compared with the coordination chemistry of the previously...
Dimeric formally two-coordinate Tl2(OR)2 (OR = OCtBu2Ph and OCtBu2(3,5-Me2C6H3)) complexes serve as convenient precursors for the variety of transition metal bis(alkoxide) and mono(alkoxide) complexes.
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