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Industrial activities have a huge potential for waste heat recovery. In spite of its high potential, industrial waste heat (IWH) is currently underutilised. This may be due, on one hand, to the technical and economic difficulties in applying conventional heat recovery methods and, on the other, the temporary or geographical mismatch between the energy released and its heat demand. Thermal energy storage (TES) is a technology which can solve the existing mismatch by recovering the IWH and storing it for a later use. Moreover, the use of recovered IWH leads to a decrease of CO 2 emissions and to economic and energy savings. Depending on the distance between the IWH source and the heat demand, TES systems can be placed on-site or the IWH can be transported by means of mobile TES systems, to an off-site heat demand. Around 50 industry case studies, in which both on-site and off-site recovery systems are considered are here reviewed and discussed taking into account the characteristics of the heat source, the heat, the TES system, and the economic, environmental and energy savings. Besides, the trends and the maturity of the cases reviewed have been considered. On-site TES systems in the basic metals manufacturing are the technology and industrial sector which has focused the most attention among the researchers, respectively. Moreover, water (or steam), erythritol and zeolite are the TES materials used in most industries and space comfort and electricity generation are the most recurrent applications.

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Today, one of the biggest challenges our society must face is the satisfactory supply, dispatchability and management of the energy. Thermal Energy Storage (TES) has been identified as a breakthrough concept in industrial heat recovery applications and development of renewable technologies such as concentrated solar power (CSP) plants or compressed air energy storage (CAES). A wide variety of potential heat storage materials has been identified depending on the implemented TES method: sensible, latent or thermochemical. Although no ideal storage material has been identified, several materials have shown a high potential depending on the mentioned considerations. Despite the amount of studied potential heat storage materials, the determination of new alternatives for next generation technologies is still open. One of the main drawbacks in the development of storage materials is their cost. In this regard, this paper presents the review of waste materials and by-products candidates which use contributes in lowering the total cost of the storage system and the valorization of waste industrial materials have strong environmental and societal benefits such as reducing the landfilled waste amounts, reducing the greenhouse emissions and others. This article reviews different industrial waste materials that have been considered as potential TES materials and have been characterized as such. Asbestos containing wastes, fly ashes, by-products from the salt industry and from the metal industry, wastes from recycling steel process and from copper refining process and dross from the aluminum industry, and municipal wastes (glass and nylon) have been considered. Themophysical properties, characterization and experiences using these candidates are discussed and compared. This review shows that the revalorization of wastes or by-products as TES materials is possible, and that more studies are needed to achieve industrial deployment of the idea.

a b s t r a c tIn accordance to the current worldwide trend of reducing CO 2 emissions and to make the industry more competitive incrementing its efficiency, some countries are starting to quantify their quantity of Industrial