Coal-derived power comprises over 39% of the world’s power production. Therefore, a mass volume of coal combustion byproducts are generated and shifted the extra burden onto the economy and environment. Circulating fluidized bed combustion (CFBC) has been found to be a clean and ultimate technology for Korea’s coal-fired power plants to have effective power generation from low-grade imported coal with reduced emissions. Efforts have been made to broaden the utilization of CFBC coal ash, and to promote sustainable development of CFBC technology. Investigations provided numerous evidences for coal ash to be a potential deposit for rare earths reclamation. However, the basic characteristics and the methods of rare earth mining from the CFBC bottom ash lack detailed understanding and are poorly reported. This study highlighted an insight of the CBFC bottom ash with respect to REEs concentration. Moreover, agents were tested as a means for leaching REEs from Samcheok CFBC bottom ash. The leaching tests were performed in relation to variations in concentration, time and temperature. The results were applied to identify suitable processes to leach REEs from the ash and clarify the potential valuation of CFBC bottom ash. The leaching conditions attained by ANOVA analysis for hydrochloric concentration, temperature, and time of 2 mol L−1, 80 °C, and 12 h, were found to provide a maximum extraction of yttrium, neodymium and dysprosium of 62.1%, 55.5% and 65.2%, respectively.
Heap leaching is a low-cost technology used in industrial mining to recover precious metals such as gold and uranium, along with several other highly sought after metals like copper, from their primary resources (ores and minerals). For many decades, there has been a growing demand for heap leaching due to its environmental benefits. Heap leaching provides mining operators with a benign, effective and economical solution for the environment and produces only minor emissions from furnaces. The cost of the heap leaching process is low, making this process an attractive option from a financial standpoint. Here, we shall present a brief review of the heap leaching process when applied to the extraction of different metals from primary resources (ores and minerals). This paper presents a roadmap to satisfy future national demands for rare earth elements (REEs). This heap leaching process is applicable for the recovery of REEs from secondary resources such as mining and coal residues. Heap leaching plays a significant role in the recovery of critical elements which are used in clean and green energy applications. In the mining sector, heap leaching is a distinguished method for the recovery of valuable/beneficial metals from low-quality ore. In the present study, we shall report briefly on the heap leaching technologies for valuable metal recovery with economic advantages.
In this study, we present a low-cost and simple method to treat spent lead–acid battery wastewater using quicklime and slaked lime. The sulfate and lead were successfully removed using the precipitation method. The structure of quicklime, slaked lime, and resultant residues were measured by X-ray diffraction. The obtained results show that the sulfate removal efficiencies were more than 97% for both quicklime and slaked lime and the lead removal efficiencies were 49% for quicklime and 53% for slaked lime in a non-carbonation process. After the carbonation step, the sulfate removal efficiencies were slightly decreased but the lead removal efficiencies were 68.4% for quicklime and 69.3% for slaked lime which were significantly increased compared with the non-carbonation process. This result suggested that quicklime, slaked lime, and carbon dioxide can be a potential candidate for the removal of sulfate and lead from industrial wastewater treatment.
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